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. 2024 Sep 14;14(1):52. doi: 10.1007/s13659-024-00476-6

Table 2.

The glycosidic linkages of DRP-I and DRP-II determined by methylation analysis

tR/min Methylated sugar Mass fragments (m/z) Type of linkage
7.720 2,3,4-Me3-Xylp 59,73,87,101,102,117,118,161,162 T-Xylp
11.107 2,4-Me2-Fucp 59,72,89,101,113,118,131,160,234,243  → 3)-Fucp-(1 → 
11.711 2,3,4,6-Me4-Glcp/Manp 43,71,87,102,118,129,145,162,205 T-Glcp/Manp
12.379 2,3,4,6-Me4-Galp 43,71,87,102,118,129,145,162,205 T-Galp
15.082 2,4,6-Me3-Galp 59,74,87,101,118,129,161,174,202,234,277  → 3)-Galp-(1 → 
15.370 2,3,6-Me3-Manp 59,71,87,102,118,129,143,162,173,233  → 4)-Manp-(1 → 
17.235 2,3,4-Me3-Galp 59,71,87,99,118,129,162,173,189,233  → 6)-Galp-(1 → 
20.857 3,4-Me3-Galp 74,87,99,100,129,130,189,190,233  → 2,6)-Galp-(1 → 
20.980 3,4-Me3-Manp 43,87,101,118,129,139,160,189,234  → 2,6)-Manp-(1 →