The k and Γ for in the reaction of CBF with ·OH and SO4·− at 298 K.
| Reaction | k 298K (M−1 s−1) | Γ (%) | Reaction | k 298K (M−1 s−1) | Γ (%) |
|---|---|---|---|---|---|
| CBF + SO4·− → IM1-1(SO4) | 2.46 × 107 | 0.54 | CBF + ·OH → IM1-1(OH) | 1.49 × 107 | 0.33 |
| CBF + SO4·− → IM1-2(SO4) | 2.88 × 106 | 0.06 | CBF + ·OH → IM1-2(OH) | 1.89 × 106 | 0.04 |
| CBF + SO4·− → IM1-3(SO4) | 1.09 × 109 | 23.86 | CBF + ·OH → IM1-3(OH) | 1.03 × 108 | 2.26 |
| CBF + SO4·− → IM1-4(SO4) | 1.99 × 107 | 0.44 | CBF + ·OH → IM1-4(OH) | 1.81 × 106 | 0.04 |
| CBF + SO4·− → IM1-5(SO4) | 1.47 × 108 | 3.22 | CBF + ·OH → IM1-5(OH) | 5.54 × 106 | 0.12 |
| CBF + SO4·− → IM1-6(SO4) | 4.73 × 108 | 10.38 | CBF + ·OH → IM1-6(OH) | 7.93 × 108 | 16.20 |
| CBF + SO4·− → IM1-7(SO4) | 2.77 × 10−4 | 0 | CBF + ·OH → IM1-7(OH) | 9.13 × 10−4 | 0 |
| k addSO4·− | 1.75 × 109 | 38.51 | k add·OH | 8.66 × 108 | 18.99 |
| CBF + SO4·− → IM1-8 + HSO4·− | 1.42 | 0 | CBF + ·OH → IM1-8 + H2O | 3.95 × 104 | 0 |
| CBF + SO4·− → IM1-9 + HSO4·− | 1.07 × 101 | 0 | CBF + ·OH → IM1-9 + H2O | 5.36 × 103 | 0 |
| CBF + SO4·− → IM1-10 + HSO4·− | 1.89 × 10−2 | 0 | CBF + ·OH → IM1-10 + H2O | 9.48 × 103 | 0 |
| CBF + SO4·− → IM1-11 + HSO4·− | 8.49 × 103 | 0 | CBF + ·OH → IM1-11 + H2O | 1.87 × 102 | 0 |
| CBF + SO4·− → IM1-12 + HSO4·− | 4.46 × 104 | 0 | CBF + ·OH → IM1-12 + H2O | 1.65 × 106 | 0.04 |
| CBF + SO4·− → IM1-13 + HSO4·− | 3.61 × 102 | 0 | CBF + ·OH → IM1-13 + H2O | 4.31 × 106 | 0.10 |
| CBF + SO4·− → IM1-14 + HSO4·− | 1.24 × 103 | 0 | CBF + ·OH → IM1-14 + H2O | 5.82 × 105 | 0.01 |
| CBF + SO4·− → IM1-15 + HSO4·− | 1.91 × 109 | 41.84 | CBF + ·OH → IM1-15 + H2O | 2.32 × 107 | 0.51 |
| k absSO4·− | 1.91 × 109 | 41.84 | k abs·OH | 2.98 × 107 | 0.66 |