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. 2024 Sep 4;15(39):16006–16014. doi: 10.1039/d4sc04243c

Polymerization of phenylacetylene.

graphic file with name d4sc04243c-u1.jpg
Entry Monomer Catalyst [PhCCH]: [Cat] Time Yield (%) M n (kDa) Đ
1 PA 6 10 000 15 min 94 30.8 2.2
2 PA 6 5000 15 min 96 69 1.8
3 PA 8 1000 12 h 94 62.9 1.6
4 PA 8 100 2 h 94 272 1.3
5 PA 10 1000 12 h 37 108 1.5
6 PA 10 1000 12 h 19 115 1.5
7 PA 11 500 12 h 59 48 4.1
8 PA 11 100 12 h 21 30 3.4
9 PA 12 50 12 h 16 32 3.6
10 PA 12 250 12 h 7 38 3.5