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. 2024 Aug 25;14(9):184. doi: 10.3390/membranes14090184

Table 1.

MXene/CNT composites obtained by different methods and their features.

Composite Synthesis Method Additive Morphological Features Adsorption Capabilities Source
Ti3C2Tx/CNTs Electrostatic self-assembly basalt fiber-reinforced polymer, epoxy Uniform thickness;
Basalt fibers tightly embedded in matrix composites
Synergistic effect of MXene/CNT/epoxy composite;
High stability in alkaline environments
[118]
Ti3C2Tx/CNTs CVD - Uniform growth CNTs with a diameter from 40 to 90 nm;
Ti3C2Tx layered particles, a common network of Ti3C2Tx/CNTs
n/a [123]
Ti3C2Tx/CNTs-cetyltrimethylammonium bromide on nanofiltration membrane Vacuum-assisted filtration cetyltrimethylammonium bromide Membranes with a layered structure had a larger gap between them;
The interfacial adhesion force was increased by 6 times compared to the MXene membrane
Membrane has excellent mechanical strength and solvent resistance during molecular sieving;
The permeability of pure water increased up to 5 times, with 20.09 L/m2·h·bar to 100.89 L/m2·h·bar
[119]
Ti3C2Tx/CNTs Electrophoretic deposition - CNT provides maximum ion access to ion intercalation sites by increasing the distance between the layers of the MXene nanolayer. Efficient and fast hybrid capacitive deionization;
High fiber hydrophilicity;
Specific capacity (178 F/g);
Low degreasing resistance;
High electrochemical stability (90%);
After 1500 cycles and maximum Na+ diffusion coefficient;
It can provide an energy-efficient desalination process and outstanding desalination stability with a retention rate of 89% after 40 cycles
[126]
Ti3C2Tx/functionalized CNTs Thermal treatment PDA-modified α-Al2O3 1D CNTs are well dispersed and embedded in two-dimensional MXene nanoliths;
The formation of a homogeneous network and continuous three-dimensional (3D) labyrinthine short mass transfer channels
Improved permeability;
Pronounced ability to suppress swelling;
Stability
[127]
Dual-phase MoS2/Ti3C2Tx/CNT One-step bisolvent solvothermal synthesis technique 1 T enriched-MoS2 Triple hybrid structure;
Two-phase MoS2 (DP-MoS2) is formed directly on MXene, while CNTs act as crosslinking between 2D islands;
MoO2 suppresses oxidation of MXene and rearrangement of 2D layers
Increasing the surface area to 32 m2/g [129]
Ti3C2/knotted CNTs CVD the catalyst Ni–Mn–Al–O Formation of a three-dimensional network architecture;
CNT nodules with a size of 200 ± 20 nm;
The average Ti3C2 flake size is ~250 nm;
Ti3C2/CNT in the form of a sponge
n/a [122]
Ti3C2Tx/CNT/waterborne polyurethane Sonication waterborne polyurethane Free and uniform film with a thickness of 90 µm; n/a [130]
Ti3C2Tx/
Carboxylated-CNTs microspheres
Self-assembly - Layered structure of Ti3C2Tx MXene nanosheets with thickness 1.32 nm;
Spherical hierarchical 3D structure of composite with typical shrinkage morphology
BET Surface Area 48.64 m2/g;
Pore Volume 0.1462 cm3/g;
Pore Size 24.19 nm
[125]
Ti3C2Tx/CNTs Dip-coating thermoplastic polyurethane nonwoven fabric Hypersensitive microcrack structure;
Porous fibrous mesh structure
Stability at high temperatures;
The synergistic effect of the MXene/CNTs conductive coating
[128]
MXene/sodium lignosulfonate CNT Self-assembly sodium lignosulfonate, polyethersulfone substrate pretreated with dopamine Uniform distribution;
Structural integrity
The MB and CR dyes retention efficiency was more than 99% with a permeation flux of 51.6 L/m2·h·bar;
This membrane shows electrocatalytic efficiency, whereby it degrades various organic dyes (MO, MB, MG, RhB) within 1 h;
It has 80% recovery capacity
[134]