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Eley–Rideal type mechanism for the formation of CH3OH on Pd-CeO2 (A–C, black path) and Pd-iC-CeO2 (a–c, blue path). The first step of the mechanism involves the formation of CH2OH and then the formation of CH3OH. The adsorption energy of each stable state and the activation energy associated with the transition states relative to their precursor states are included.
