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. 2024 Sep 14;87(9):2281–2291. doi: 10.1021/acs.jnatprod.4c00730

Table 5. 1H NMR (500 MHz) Data for Compounds 1115 in CDCl3.

  δH,mult. (Jin Hz)
No. 11 12 13 14 + 15
1 1.10, m 1.11, m 1.05, m 1.11, m
2.55, m 2.52, m 2.45, m 2.52, m
2 1.67, m 1.73, m 1.71, m 1.74, m
1.76, m 1.74, m
3 3.30, dd (10.3, 5.5) 3.30, m 3.28, m 3.30, dd (10.4, 5.5)
5 1.64, m 1.64, dd (13.5, 4.9) 1.65, m  
6 2.44, m 2.48, m 2.49, m 1.65, m
2.55, m 2.52, m 2.54, m 2.48, m
12 2.48, d (18.7) 2.43, d (19.0) 2.44, d (18.7) 2.44, m
2.67, d (18.7) 2.65, d (19.0) 2.68, d (18.7) 2.64, m
15 1.66, m 1.66, m 1.65, m 1.65, m
2.15, t (11.2) 2.13, m 2.16, m 2.14, m
16 1.41, m 1.38, m 1.40, m 1.40, m
2.02, m 2.02, m 2.04, m 2.02, m
17 1.68, m 1.65, m 1.67, m 1.65, m
18 0.95, s 0.92, s 0.93, s 0.92, s
19 1.31, s 1.31, s 1.31, s 1.30, s
20 1.53, m 1.46, m 1.55, m 1.46, m
21 0.87, d, 6.5 0.92, d (6.8) 0.94, d (6.4) 0.87, d (6.4)
22 1.73, m 0.99, m 1.24, m 1.10, m
  2.27, dt, (13.7, 3.3) 1.44, m 1.65, m 1.50, m
23 5.48, m 1.46, m 2.29, m 1.37, m
1.65, m 2.42, m 1.65, m
24 5.40, d (15.8) 2.40, t (7.0) 6.45, t (7.3) 4.27, t (6.5)
25 1.25, s      
26 1.25, s 2.13, s 9.40, s 5.02, br s
5.04, m
27     1.75, s 1.74, s
28 1.03, s 1.03, s 1.03, s 1.03, s
29 0.90, s 0.91, s 0.90, s 0.90, s
30 1.09, s 1.08, s 1.09, s 1.08, s
25-OCH3 3.15, s