Table 5. 1H NMR (500 MHz) Data for Compounds 11–15 in CDCl3.
|
δH,mult. (Jin Hz) |
||||
|---|---|---|---|---|
| No. | 11 | 12 | 13 | 14 + 15 |
| 1 | 1.10, m | 1.11, m | 1.05, m | 1.11, m |
| 2.55, m | 2.52, m | 2.45, m | 2.52, m | |
| 2 | 1.67, m | 1.73, m | 1.71, m | 1.74, m |
| 1.76, m | 1.74, m | |||
| 3 | 3.30, dd (10.3, 5.5) | 3.30, m | 3.28, m | 3.30, dd (10.4, 5.5) |
| 5 | 1.64, m | 1.64, dd (13.5, 4.9) | 1.65, m | |
| 6 | 2.44, m | 2.48, m | 2.49, m | 1.65, m |
| 2.55, m | 2.52, m | 2.54, m | 2.48, m | |
| 12 | 2.48, d (18.7) | 2.43, d (19.0) | 2.44, d (18.7) | 2.44, m |
| 2.67, d (18.7) | 2.65, d (19.0) | 2.68, d (18.7) | 2.64, m | |
| 15 | 1.66, m | 1.66, m | 1.65, m | 1.65, m |
| 2.15, t (11.2) | 2.13, m | 2.16, m | 2.14, m | |
| 16 | 1.41, m | 1.38, m | 1.40, m | 1.40, m |
| 2.02, m | 2.02, m | 2.04, m | 2.02, m | |
| 17 | 1.68, m | 1.65, m | 1.67, m | 1.65, m |
| 18 | 0.95, s | 0.92, s | 0.93, s | 0.92, s |
| 19 | 1.31, s | 1.31, s | 1.31, s | 1.30, s |
| 20 | 1.53, m | 1.46, m | 1.55, m | 1.46, m |
| 21 | 0.87, d, 6.5 | 0.92, d (6.8) | 0.94, d (6.4) | 0.87, d (6.4) |
| 22 | 1.73, m | 0.99, m | 1.24, m | 1.10, m |
| 2.27, dt, (13.7, 3.3) | 1.44, m | 1.65, m | 1.50, m | |
| 23 | 5.48, m | 1.46, m | 2.29, m | 1.37, m |
| 1.65, m | 2.42, m | 1.65, m | ||
| 24 | 5.40, d (15.8) | 2.40, t (7.0) | 6.45, t (7.3) | 4.27, t (6.5) |
| 25 | 1.25, s | |||
| 26 | 1.25, s | 2.13, s | 9.40, s | 5.02, br s |
| 5.04, m | ||||
| 27 | 1.75, s | 1.74, s | ||
| 28 | 1.03, s | 1.03, s | 1.03, s | 1.03, s |
| 29 | 0.90, s | 0.91, s | 0.90, s | 0.90, s |
| 30 | 1.09, s | 1.08, s | 1.09, s | 1.08, s |
| 25-OCH3 | 3.15, s | |||