Table 6. 13C NMR (125 MHz) Data for Compounds 11–15 in CDCl3.
|
δC,type |
||||
|---|---|---|---|---|
| No. | 11 | 12 | 13 | 14, 15 |
| 1 | 34.1, CH2 | 34.1, CH2 | 34.1, CH2 | 34.1, CH2 |
| 2 | 27.6, CH2 | 27.6, CH2 | 27.6, CH2 | 27.6, CH2 |
| 3 | 78.1, CH | 78.2, CH | 78.1, CH | 78.1, CH |
| 4 | 38.7, C | 38.8, C | 38.7, C | 38.7, C |
| 5 | 48.7, CH | 48.7, CH | 48.6, CH | 48.6, CH |
| 6 | 35.9, CH2 | 36.0, CH2 | 35.9, CH2 | 35.9, CH2 |
| 7 | 200.0, C | 199.9, C | 200.0, C | 200.0, C |
| 8 | 149.9, C | 150.0, C | 149.9, C | 149.9, C |
| 9 | 154.9, C | 154.9, C | 154.9, C | 155.0, C |
| 10 | 38.2, C | 38.3, C | 38.2, C | 38.2, C |
| 11 | 201.8, C | 202.0, C | 201.7, C | 202.0, C |
| 12 | 51.5, CH2 | 51.6, CH2 | 51.6, CH2 | 51.5/51.6, CH2 |
| 13 | 45.3, C | 45.3, C | 45.2, C | 45.3, C |
| 14 | 48.0, C | 48.1, C | 48.1, C | 48.1, C |
| 15 | 31.9, CH2 | 32.0, CH2 | 31.9, C | 31.9, CH2 |
| 16 | 28.1, CH2 | 28.3, CH2 | 28.3, CH2 | 27.9, CH2 |
| 17 | 49.2, CH | 49.5, CH | 48.6, CH | 48.6, CH |
| 18 | 18.8, CH3 | 18.7, CH3 | 18.8, CH3 | 18.6, CH3 |
| 19 | 17.9, CH3 | 17.9, CH3 | 17.9, CH3 | 17.9, CH3 |
| 20 | 36.2, CH | 36.1, CH | 35.9, CH | 35.8, CH |
| 21 | 18.9, CH3 | 18.5, CH3 | 18.5, CH3 | 18.8, CH3 |
| 22 | 38.2, CH2 | 34.6, CH2 | 34.1, CH2 | 30.7/31.0, CH2 |
| 23 | 128.2, CH | 21.0, CH2 | 26.4, CH2 | 27.6, CH2 |
| 24 | 137.3, CH | 44.0, CH2 | 154.4, CH | 89.5/90.1, CH |
| 25 | 74.9, C | 208.8, C | 139.6, C | 144.0/143.7, C |
| 26 | 26.0, CH3 | 30.0, CH3 | 195.3, CH | 114.3/114.8, CH2 |
| 27 | 26.0, CH3 | 9.4, CH3 | 17.2/17.4, CH3 | |
| 28 | 27.7, CH3 | 27.8, CH3 | 27.7, CH3 | 27.7, CH3 |
| 29 | 15.2, CH3 | 15.2, CH3 | 15.3, CH3 | 15.2, CH3 |
| 30 | 24.1, CH3 | 24.2, CH3 | 24.1, CH3 | 24.2, CH3 |
| 25–OCH3 | 50.4 | |||