Table 10:

Experimental standard enthalpies of formation for the liquid phase ${\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(\text{l}\right)$ and the ideal gas ${\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(\text{g}\right)$, the computed enthalpies of formation for the ideal gas ${\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }$ (g; calc) and corresponding recommended values for brominated hydrocarbons at the reference temperature $T=298.15\text{K}$

Compound (CASRN)	$\frac{{\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(1\right)}{\text{kJ}\cdot {\text{mol}}^{-1}}$	$\frac{{\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(\text{g}\right)}{\text{kJ}\cdot {\text{mol}}^{-1}}$	$\frac{{\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(\text{g}\right)}{\text{kJ}\cdot {\text{mol}}^{-1}}$	$\frac{{\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(\text{l}\right)}{\text{kJ}\cdot {\text{mol}}^{-1}}$	$\frac{{\Delta }_{\text{f}}{\text{H}}_{\text{m}}^{\circ }\left(\text{g}\right)}{\text{kJ}\cdot {\text{mol}}^{-1}}$
	Experimental		ab initio	Recommended
Bromo- and dibromopropanes
1-bromopropane (106-94-5)	−(116.0 ± 0.5)	−(83.8 ± 0.5)	−(85.6 ± 2.6)	−(116.0 ± 0.5)	−(83.8 ± 0.5)
2-bromopropane (75-26-3)	−(126.3 ± 0.7)	−(95.9 ± 0.7)	−(96.6 ± 2.6)	−(126.3 ± 0.7)	−(95.9 ± 0.7)
1,1-dibromopropane (598-17-4)	−(93.9 ± 1.0)		−(53.9 ± 2.7)	−(93.9 ± 1.0)	−(53.9 ± 2.7)
1,2-dibromopropane (78-75-1)	−(113.8 ± 0.9)	−(72.1 ± 0.9)	−(72.7 ± 2.7)	−(113.8 ± 0.9)	−(72.1 ± 0.9)
1,3-dibromopropane (109-64-8)	−(109.1 ± 0.9)	−(61.6 ± 0.9)	−(64.0 ± 2.7)	−(109.1 ± 0.9)	−(61.6 ± 0.9)
2,2-dibromopropane (594-16-1)		−(70.4 ± 3.0)	−(68.3 ± 2.7)		−(68.3 ± 2.7)
C3H5Br compounds
(Z)-1-bromopropene (590-13-6)		38.4 ± 2.7	39.1 ± 2.6		38.4 ± 2.7
(E)-1-bromopropene (590-15-8)		40.4 ± 2.6	41.1 ± 2.6		40.4 ± 2.6
bromopropene (557-93-7)		34.5 ± 2.7	32.9 ± 2.6		34.5 ± 3.8
3-bromopropene (106-95-6)	13.8 ± 2.3	46.1 ± 2.3	44.2 ± 2.6	13.8 ± 2.3	46.1 ± 2.3
bromocyclopropane (4333-56-6)			79.6 ± 2.6		79.6 ± 2.6
Bromobutanes
1-bromobutane (109-65-9)	−(142.6 ± 1.0)	−(105.8 ± 1.0)	−(106.2 ± 2.6)	−(142.6 ± 1.0)	−(105.8 ± 1.0)
2-bromobutane (78-76-2)	−(153.7 ± 0.3)	−(119.2 ± 0.3)	−(117.9 ± 2.6)	−(153.7 ± 0.3)	−(119.2 ± 0.3)
1-bromo-2-methylpropane (78-77-3)	−(148.4 ± 1.3)	−(113.5 ± 1.3)	−(114.3 ± 2.6)	−(148.4 ± 1.3)	−(113.5 ± 1.3)
2-bromo-2-methylpropane (507-19-7)	−(163.7 ± 1.1)	−(131.7 ± 1.1)	−(131.7 ± 2.6)	−(163.7 ± 1.1)	−(131.7 ± 1.1)
bromocyclobutane (4399-47-7)	−(7.4 ± 4.4)		32.7 ± 2.6	−(7.4 ± 4.4)	32.7 ± 2.6
1,2-dibromobutane (533-98-2)	−(142.9 ± 3.4)	−(96.9 ± 3.3)	−(94.6 ± 2.7)	−(140.6 ± 2.8)	−(94.6 ± 2.7)
1,3-dibromobutane (107-80-2)	−(149.2 ± 3.4)	−(99.8 ± 3.5)	−(97.7 ± 2.7)	−(147.0 ± 2.9)	−(97.7 ± 2.7)
1,4-dibromobutane (110-52-1)	−(141.3 ± 3.4)	−(88.2 ± 3.4)	−(86.2 ± 2.7)	−(139.3 ± 2.7)	−(86.2 ± 2.7)
meso-2,3-dibromobutane (5780-13-2)	−(150.2 ± 3.4)		−(102.5 ± 2.7)	−(150.2 ± 3.4)	−(102.5 ± 2.7)
dl-2,3-dibromobutane (598-71-0)	−(151.9 ± 3.4)		−(103.3 ± 2.7)	−(151.9 ± 3.4)	−(103.3 ± 2.7)
1,2-dibromo-2-methylpropane (594-34-3)	−(156.6 ± 0.6)	−(113.3 ± 0.6)	−(107.8 ± 2.7)	−(151.1 ± 2.7)	−(107.8 ± 2.7)
1,3-dibromo-2-methylpropane (28148-04-1)	−(147.8 ± 0.6)	−(101.4 ± 1.6)	−(93.0 ± 2.7)	−(139.3 ± 3.1)	−(93.0 ± 2.7)