Table 7:

Experimental standard enthalpies of formation for the liquid phase ${\Delta }_{\text{f}}{H}_{\text{m}}^{\circ }\left(\text{l}\right)$ and the ideal gas ${\Delta }_{\text{f}}{H}_{\text{m}}^{\circ }\left(\text{g}\right)$, experimental standard enthalpies of vaporization or sublimation ${\Delta }_1^{\text{g}}{H}_{\text{m}}^{\circ }\left(\text{l}\right)$, and the computed enthalpies of formation for the ideal gas ${\Delta }_{\text{f}}{H}_{\text{m}}^{\circ }(\text{g}$; calc) for brominated hydrocarbons at the reference temperature $T=298.15$^a

Method	$T$ range $/\text{K}$	$\frac{{\Delta }_{\text{f}}{H}_{\text{m}}^{\circ }\left(\text{l}\right)}{\mathrm{kJ}\cdot {\mathrm{mol}}^{-1}}$	$\frac{{\Delta }_{\text{l}}^{\text{g}}{H}_{\text{m}}^{\circ }}{\mathrm{kJ}\cdot {\mathrm{mol}}^{-1}}$	$\frac{{\Delta }_{\text{f}}{H}_{\text{m}}^{\circ }\left(\text{g}\right)}{\mathrm{kJ}\cdot {\mathrm{mol}}^{-1}}$	Year	Reference	$\frac{{\Delta }_{\text{f}}{H}_{\text{m}}^{\circ }(\text{g};\mathrm{calc})}{\mathrm{kJ}\cdot {\mathrm{mol}}^{-1}}$
Bromo- and dibromopropanes
1-bromopropane (106-94-5)
R	367			−76.8 ± 0.7	1950	Lacher et al. 132
R	401			−89.9 ± 1.4	1957	Lacher et al. 133
C	298.2	−(123.5 ± 1.4)			1961	Bjellerup 7,102
E	423.9 to 514.0			−(83.6 ± 1.2)	1964	Rozhnov and Andreevskii 134
R	523			−(83.8 ± 0.6)	1965	Davies et al. 135
E	273.2 to 303.2			−(84.0 ± 1.6)	1974	Alenin et al. 136,137
		−(116.0 ± 0.5)	32.2 ± 0.1	−(83.8 ± 0.5)			−(85.6 ± 2.6)
2-bromopropane (75-26-3)
R	367			−(99.7 ± 1.0)	1950	Lacher et al. 132
R	401			−(100.7 ± 0.7)	1957	Lacher et al. 133
C	298.2	−(128.2 ± 1.8)			1961	Bjellerup 7,102
E	393.8 to 447.5			−(97.7 ± 3.4)	1963	Rozhnov and Andreevskii 138
R	523			−(95.6 ± 1.0)	1965	Davies et al. 135
MS	0			−(95.9 ± 0.8)	2010	Stevens et al. 139
MS	0			−(94.9 ± 1.5)	2010	Stevens et al. 139
		−(126.3 ± 0.7)	30.3 ± 0.1	−(95.9 ± 0.7)			−(96.6 ± 2.6)
1,1-dibromopropane (598-17-4)
E	373 to 543	−(93.9 ± 1.0)			1974	Izmailov et al. 140,141
		−(93.9 ± 1.0)					−(53.9 ± 2.7)
1,2-dibromopropane (78-75-1)
R	355			−(72.1 ± 0.9)	1938	Conn et al. 7,83
		−(113.8 ± 0.9)	41.7 ± 0.1	−(72.1 ± 0.9)			−(72.7 ± 2.7)
1,3-dibromopropane (109-64-8)
E	273 to 403	−(109.1 ± 0.9)			1971	Sharonov and Rozhnov 93
		−(109.1 ± 0.9)	47.5 ± 0.1	−(61.6 ± 0.9)			−(64.0 ± 2.7)
2,2-dibromopropane (594-16-1)
E	397.7 to 446.2			−(70.4 ± 3.0)	1971	Sharonov and Rozhnov 142
				−(70.4 ± 3.0)			−(68.3 ± 2.7)
C3H5Br compounds
(Z)-1-bromopropene (590-13-6)
MS	0			38.4 ± 2.7	2012	Borkar et al. 143
				38.4 ± 2.7			39.1 ± 2.6
(E)-1-bromopropene (590-15-8)
MS	0			40.4 ± 2.6	2012	Borkar et al. 143
				40.4 ± 2.6			41.1 ± 2.6
2-bromopropene (557-93-7)
MS	0			34.5 ± 2.7	2012	Borkar et al. 143
				34.5 ± 2.7			32.9 ± 2.6
3-bromopropene (106-95-6)
R	298.2	15.0 ± 2.6			1949	Gellner and Skinner 91
R	308.2	10.6 ± 4.4			1981	Holm 92 b
		13.8 ± 2.3	32.3 ± 0.3	46.1 ± 2.3			44.2 ± 2.6
bromocyclopropane (4333-56-6)
R	308.2	See text			1981	Holm 92,144 b
MS	0			See text	2012	Borkar et al. 143
							79.6 ± 2.6
Bromobutanes
1-bromobutane (109-65-9)
C	298.2	−(143.1 ± 1.3)			1961	Bjellerup 7,97
E	298.2 to 513.7			−(105.2 ± 1.4)	1968	Peshchenko and Andreevskii 98
		−(142.6 ± 1.0)	36.9 ± 0.1	−(105.8 ± 1.0)			−(106.2 ± 2.6)
2-bromobutane (78-76-2)
R	367			−(119.3 ± 0.6)	1952	Lacher et al. 7,101
R	373			−(119.7 ± 0.5)	1952	Lacher et al. 7,101
R	373			−(119.0 ± 0.6)	1952	Lacher et al. 7,101
C	298.2	−(154.4 ± 1.3)			1961	Bjellerup 7,97
E	405.2 to 433.0			−(118.5 ± 0.6)	1968	Peshchenko and Andreevskii 103
		−(153.7 ± 0.3)	34.5 ± 0.1	−(119.2 ± 0.3)			−(117.9 ± 2.6)
1-bromo-2-methylpropane (78-77-3)
R	308.2	−(151.6 ± 4.4)			1981	Holm 92 b
E	273.2 to 526.2	−(148.1 ± 1.3)			1974	Nesterova and Rozhnov 104
		−(148.4 ± 1.3)	34.9 ± 0.1	−(113.5 ± 1.3)			−(114.3 ± 2.6)
2-bromo-2-methylpropane (507-19-7)
E	375.0 to 531.7			−(131.9 ± 2.1)	1937	Kistiakowsky and Stauffer 7,105
E	372.9 to 483.6			−(131.7 ± 1.3)	1957	Howlett 7,106
		−(163.7 ± 1.1)	31.9 ± 0.1	−(131.7 ± 1.1)			−(131.7 ± 2.6)
bromocyclobutane (4399-47-7)
R	308.2	−(7.9 ± 4.4)			1981	Holm 92 b
		−(7.9 ± 4.4)					32.7 ± 2.6
1,2-dibromobutane (533-98-2)
R	355			−(93.5 ± 1.7)	1938	Conn et al. 7,83
R	300	−(133.4 ± 2.7)			1941	Lister 128
C	298.2	−(146.2 ± 2.3)			1961	Bjellerup 7,97
		−(142.9 ± 4.5)	46.0 ± 0.6	−(96.9 ± 3.3)			−(94.6 ± 2.7)
1,3-dibromobutane (107-80-2)
E	275.2 to 553.2	−(149.2 ± 3.4)			1972	Nesterova et al. 145
		−(149.2 ± 3.4)	49.4 ± 0.9	−(99.8 ± 3.5)			−(97.7 ± 2.7)
1,4-dibromobutane (110-52-1)
E	275.2 to 553.2	−(141.3 ± 3.4)			1972	Rozhnov et al. 146
		−(141.3 ± 3.4)	53.1 ± 0.1	−(88.2 ± 3.4)			−(86.2 ± 2.7)
meso-2,3-dibromobutane (5780-13-2)
E	275.2 to 553.2	−(150.2 ± 3.4)			1972	Nesterova et al. 145
							−(102.5 ± 2.7)
dl-2,3-dibromobutane (598-71-0)
E	275.2 to 553.2	−(151.9 ± 3.4)			1972	Nesterova et al. 145
							−(103.3 ± 2.7)
1,2-dibromo-2-methylpropane (594-34-3)
R	298.2	−(156.6 ± 0.6)			1974	Sunner and Wulff 131
		−(156.6 ± 0.6)	43.3 ± 0.1	−(113.3 ± 0.6)			−(107.8 ± 2.7)
1,3-dibromo-2-methylpropane (28148-04-1)
E	273.2 to 553.2	−(147.8 ± 0.6)			1975	Rozhnov et al. 147
		−(147.8 ± 0.6)	46.4 ± 1.5	−(101.4 ± 1.6)			−(93.0 ± 2.7)

^aThe excluded outliers are italicized, the evaluated experimental results are in bold

^bSee Table 8