Table 8.
Thermodynamic parameters for Pb(II) adsorption onto the four adsorbents.
Sorbent | ΔHo (kJ/mol) | ΔSo (J/mol.K) | ΔGo (kJ/mol) |
||||
---|---|---|---|---|---|---|---|
298 K | 308 K | 323 K | 333 K | 343 K | |||
Bentonite y = 191.3975x–0.3308 | −1.59 | 2.57 | −2.40 | −2.44 | −2.48 | −2.51 | −2.53 |
Organobentonite y = 569.2723x-0.1752 | −4.73 | −1.47 | −4.29 | −4.28 | −4.26 | −4.24 | −4.24 |
Kaolin y = 221.2933x-1.2718 | −1.84 | −10.57 | 1.31 | 1.42 | 1.57 | 1.68 | 1.79 |
Organokaolin y = 2918.87x-11.1993 | −24.27 | −93.11 | 3.48 | 4.41 | 5.80 | 6.74 | 7.67 |