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. 2024 Oct 9;14:23521. doi: 10.1038/s41598-024-73824-8

Table 1.

Aminolysis reaction of (R)-(+)-limonene oxide with different aminesa.

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Entry Amine 2 (%)b 2’ (%)b Yield %
1 Methylamine 53 47 97
2 Hexylamine 100 n.d.c 50
3 Benzylamine 100 n.d. 50
4 Aniline 73 27 59

aReaction conditions: (R)-(+)-limonene oxide (1 eq.), amine (2 eq. for entries 1 and 4, 1.2 eq. for entries 2,3), water, 100 °C, 24 h.

bCalculated by integrating the signals in the 1H NMR spectrum of the crude reaction mixture and by considering their relative abundance. Not detected.