Table 3. Important Bond Angles (deg) of [Zn2(L1)2Cl2] (1) and [Zn2(L2)2(N3)2] (2).
| complex | 1 | 2 |
|---|---|---|
| O(1)–Zn(1)–O(2) | 78.23(12) | 75.31(14) |
| O(1)–Zn(1)–N(1) | 86.73(13) | 86.65(16) |
| O(1)–Zn(1)–N(2) | 140.61(13) | 149.78(16) |
| O(1)–Zn(1)–N(2) | 107.5(2) | |
| O(2)–Zn(1)–N(1) | 155.54(14) | 141.71(17) |
| O(2)–Zn(1)–N(2) | 97.90(13) | 97.26(16) |
| O(2)–Zn(1)–N(5) | 118.89(18) | |
| N(1)–Zn(1)–N(2) | 81.56(15) | 81.57(18) |
| N(1)–Zn(1)–N(5) | 98.55(18) | |
| N(2)–Zn(1)–N(5) | 101.8(2) | |
| O(1)–Zn(2)–O(2) | 77.74(11) | 74.15(14) |
| O(1)–Zn(2)–N(3) | 145.38(15) | 144.81(18) |
| O(1)–Zn(2)–N(4) | 95.20(15) | 98.78(17) |
| O(1)–Zn(2)–N(8) | 111.72(18) | |
| O(2)–Zn(2)–N(3) | 87.52(14) | 87.12(18) |
| O(2)–Zn(2)–N(4) | 149.77(14) | 148.89(19) |
| O(2)–Zn(2)–N(8) | 108.1(2) | |
| N(3)–Zn(2)–N(4) | 81.95(18) | 81.98(19) |
| N(3)–Zn(2)–N(8) | 102.3(2) | |
| N(4)–Zn(2)–N(8) | 102.7(2) |