Table 35. Quantified BTX Yields on Mass Basis for Catalytic Pyrolysis of Lignocellulosic Biomassa.
Entry | Feedstock | Catalyst | Reactor | Reaction conditions | Individual yield | BTX yield | Ref |
---|---|---|---|---|---|---|---|
1 | Cedar | H-ZSM-5 (40) | Fixed-bed, in situ, batch | Catalyst: 0.25 g, feed: 0.25 g, T: 500 °C, reaction time: 3 min | B: 3.9 wt% | 14.4 wt% (2022) | (888) |
T: 4.4 wt% | |||||||
X: 6.1 wt% | |||||||
2 | Wood chips | Ni-Lamellar MFI | Fixed-bed and fixed-bed, ex situ, continuous | Catalyst: 5 g, feed: 1 g, Tp: 450 °C, Tc: 420 °C, TOS: 105 min | B: 0.4 wt% | 11.6 wt% (2023) | (967) |
T: 1.8 wt% | |||||||
X: 9.4 wt% | |||||||
3 | Rape straw | Dual CaO/red mud and H-ZSM-5 | Fixed-bed and fixed-bed, ex situ, batch | Catalyst: 8 g, feed: 4 g, Tp: 450 °C, Tc: 550 °C, reaction time: 45 min | B: 3.2 wt% | 11.5 wt% (2023) | (896) |
T: 3.0 wt% | |||||||
X: 5.3 wt% | |||||||
4 | Poplar | H-ZSM-5 (30) | Frontier-TMR, in situ, batch | Catalyst: 6 mg, feed: 0.6 mg, T: 600 °C | B: 2.0 wt% | 10.6 wt% (2017) | (968) |
T: 4.3 wt% | |||||||
X: 4.3 wt% | |||||||
5 | Corn stover | H-ZSM-5 | CDS-Pyroprobe, in situ, batch | Catalyst: 5 mg, feed: 1 mg, T: 550 °C | B: 3.2 wt% | 9.8 wt% (2011) | |
T: 2.2 wt% | |||||||
X: 4.4 wt% | |||||||
6 | Switchgrass | H-ZSM-5 | CDS-Pyroprobe, in situ, batch | Catalyst: 5 mg, feed: 1 mg, T: 550 °C | B: 1.9 wt% | 8.4 wt% (2011) | (890) |
T: 3.4 wt% | |||||||
X: 3.1 wt% | |||||||
7 | Pine | Ce Mo2N-H-ZSM-5 | CDS-Pyroprobe, ex situ, batch | Catalyst: 1.5 mg, feed: 0.3 mg, Tp: 750 °C, Tc: 750 °C | B: 2.0 wt% | 8.2 wt% (2018) | (954) |
T: 3.8 wt% | |||||||
X: 2.4 wt% | |||||||
8 | Quercus mongolica | Ga/H-ZSM-5 | Fixed-bed and fixed-bed, ex situ, batch | Catalyst: 5 g, feed: 15 g, Tp: 650 °C, Tc: 550 °C, reaction time: 120 min | B: 0.5 wt% | 7.2 wt% (2021) | (876) |
T: 3.0 wt% | |||||||
o-X: 1.2 wt% | |||||||
p-X: 2.5 wt% | |||||||
9 | Bamboo residues | Fe-Zn/H-ZSM-5 | CDS-Pyroprobe, in situ, batch | Catalyst: 0.67 mg, feed: 0.33 mg, T: 500 °C | B: 0.6 wt% | 6.1 wt% (2023) | (898) |
T: 2.8 wt% | |||||||
X: 2.7 wt% | |||||||
10 | Rice straw | Ni/ZSM-5 | CDS-Pyroprobe, in situ, batch | Catalyst: 0.08 g, feed: 0.02 g, T: 500 °C | B: 1.9 wt% | 5.7 wt% (2023) | (969) |
T: 2.6 wt% | |||||||
X: 2.2 wt% | |||||||
11 | Quercus variabilis | H-ZSM-5 | CDS-Pyroprobe, in situ, batch | Catalyst: 5 mg, feed: 1 mg, T: 600 °C | B: 1.5 wt% | 5.4 wt% (2019) | (970) |
T: 3.0 wt% | |||||||
X: 0.9 wt% | |||||||
12 | Poplar sawdust | Fe-Ni/ZSM-5 | Fixed-bed, in situ, batch | Catalyst: 0.5 mg, feed: 0.5 mg, T: 550 °C, reaction time: 60 min | B: 1.1 wt% | 5.2 wt% (2022) | (971) |
T: 1.6 wt% | |||||||
X: 2.5 wt% | |||||||
13 | Palm kernel shell | Fe1/Hβ | Fixed-bed and fixed-bed, ex situ, continuous | Catalyst: 5 g, WHSV: 6 h–1, Tp: 500 °C, Tc: 500 °C, TOS: 1 h | B: 0.4 wt% | 4.7 wt% (2016) | (972) |
T: 2.0 wt% | |||||||
X: 2.3 wt% | |||||||
14 | Oak | Hierarchical H-ZSM-5 | Fluidized bed, in situ, batch | Catalyst: 5 g, feed: 4.25 g, T: 500 °C | B: 0.7 wt% | 4.6 wt% (2016) | (919) |
T: 2.0 wt% | |||||||
p-X: 1.9 wt% | |||||||
15 | Miscanthus | ZSM-5 | Spouted bed, in situ, continuous | Catalyst: 20 g, WHSV: 12 h–1, T: 600 °C | B: 1.2 wt% | 3.9 wt% (2014) | (955) |
T: 1.6 wt% | |||||||
X: 1.1 wt% |
Abbreviated aromatics include benzene (B), toluene (T), and xylenes (X). Tp: pyrolysis temperature, Tc: catalytic vapor upgrading temperature.