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. 2024 Sep 17;124(19):10701–10876. doi: 10.1021/acs.chemrev.4c00087

Table 41. Aromatics Yields for Catalytic Co-pyrolysis of Pure Glycerol with Various Co-feeds.

Entry Co-feeds Catalyst Conditions Result Ref
1 Glycerol and H2O 15%CNT-OH/H-ZSM-5/Sono Continuous fixed-bed reactor, glycerol/H2O 40/60 wt%, T: 400 °C, P: 1 atm, N2, and WHSV: 0.71 h–1 BTX peak carbon yield of 27.4 C%; catalyst lifetime of ca. 8.5 h (1076)
2 Glycerol and alcohols 20Zn@Sn/H-ZSM-5 Continuous fixed-bed reactor, glycerol/CH3OH 40/60 wt%, T: 400 °C, P: 1 atm, N2, and WHSV: 0.71 h–1 BTX peak carbon yield of 38 C%; catalyst lifetime of ca. 10.5 h (1077)
3 Glycerol and alkanes Pd1.1-Zn9.2/Y2O3-Al2O3 extruded with H-ZSM-5 and bentonite Continuous fixed-bed reactor, glycerol/hexane 50/50 wt%, T: 635 °C, P: 1 atm, steam, and WHSV: 1.5 h–1 BTX mass yield of 12.0 wt% (1078)
4 Glycerol and vegetable oil H-ZSM-5/Al2O3 (60/40 wt%) Continuous fixed-bed reactor, glycerol/oleic acid 45/55 wt%, T: 550 °C, N2, P: 1 atm, and WHSV: 1 h–1 Peak BTX yield of 26.7 C%; BTX productivity of 834 mgBTX g–1catalyst during a catalyst lifetime of ca. 11 h (1079)