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. 2024 Oct 11;20:2577–2584. doi: 10.3762/bjoc.20.216

Scheme 2.

Scheme 2

Scope for transition-metal-free synthesis of arylboronates 3 using triaylbismuthines 1 and diboron 2. Yields were determined by 1H NMR spectroscopy based on 1 as three transferable aryl groups (internal standard: 1,3,5-trioxane). Isolated yield was shown in parentheses. aCHCl3 (0.4 mL) was used as the solvent.