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. 2024 Sep 24;16(19):2696. doi: 10.3390/polym16192696

Table 1.

The HSP values of the solvents and the swelling ratios of the NBR vulcanizates.

Solvents δd, MPa1/2 δp, MPa1/2 δh, MPa1/2 q, NBR34 q, NBR39 q, NBR44
Alkanes Isooctane 14.10 0.00 0.00 0.03 0.01 0.01
Heptane 15.30 0.00 0.00 0.09 0.03 0.02
Cyclohexane 16.80 0.00 0.20 0.16 0.05 0.02
Aromatics Ethylbenzene 17.80 0.60 1.40 1.81 1.24 1.03
Toluene 18.00 1.40 2.00 2.33 1.68 1.42
Ethers Diethyl ether 14.50 2.90 4.60 0.51 0.36 0.29
THF 16.80 5.70 8.00 4.59 4.12 3.86
Esters Butyl acetate 15.60 6.20 4.90 3.35 3.19 3.14
Methyl acetate 15.50 7.20 7.60 2.63 2.71 2.79
Ketones 2-butanone 16.00 9.00 5.10 4.58 4.33 4.27
Acetone 15.50 10.40 7.00 1.94 1.41 1.17
Cyclohexanone 17.80 8.40 5.10 2.19 2.01 1.95
Nitriles Butyronitrile 15.30 12.40 5.10 2.96 2.98 3
Benzonitrile 18.80 12.00 3.30 4.39 4.46 4.45
Acetonitrile 15.30 18.00 6.10 1.07 1.4 1.68
Amides DMF 17.40 13.70 11.30 3.59 3.82 4.04