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. Author manuscript; available in PMC: 2024 Oct 22.
Published in final edited form as: Angew Chem Int Ed Engl. 2024 Jan 24;63(9):e202317711. doi: 10.1002/anie.202317711

Scheme 3.

Scheme 3.

Three proposed mechanisms of oxidation of 14α-CHO dihydrolanosterol to 24,25-dihydro FF-MAS and formic acid.[12c, 18b, 20b, 25] (A) Compound 0. (B) Compound 0 plus Baeyer-Villiger rearrangement. (C) Compound I.