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. 2024 Feb 13;2(7):282–299. doi: 10.1021/prechem.3c00115

Table 2. Summary of SCVD Synthesis of 2D TMDs.

TMDs Source materials Phase Morphology Thickness Temperature (°C) Substrate Carrier gas (sccm) Growth time [min]
MoS2 (NH4)2MoS4 + S32 2H Nanosheet 1.5–2 nm 700 SiO2/Si 300Ar 14
Na2MoO4 + NaOH + S33 2H Nanosheet 2.07 nm 800 Sapphire   2
(NH4)2MoO4 + KOH + S22 2H Film 0.7 nm 750 Sapphire/SiO2/Si 30Ar 10
MoO3 + NH4OH + S34 2H Nanosheet Monolayer 760–880 Glass 150Ar 5
(NH4)6Mo7O24·4H2O + S35 2H Film 0.6–2.5 nm 800 SiO2/Si 100Ar 10
Na2MoO4·2H2O + C12H25SH36 2H Nanosheet Monolayer 850 SiO2/Si 10Ar 60
(NH4)2MoO4 + KI + S37 2H Film 1 nm 720 SiO2/Si 30Ar 3–5
(NH4)2MoS417 2H Film 2 nm 1000 Sapphire, SiO2/Si 80%Ar/20%H2 30
(NH4)2MoO4 + S29 2H Nanosheet 0.78 nm 750 Sapphire Ar 20
(NH4)2MoS438 2H Film 2–30 nm 700 SiO2/Si 96%Ar/4% H2 60
Na2MoO4·2H2O + (C2H5)2S39 2H Film 0.7 nm 850 Sapphire, SiO2/Si 350Ar/10 H2 20
Na2MoO4 + Mo(CO)6 + CH3SSCH340 2H Film 0.9 nm 850 SiO2/Si 350Ar/15H2 20
MoO3 + NH4OH + S41 2H Film 0.8 nm 800 SiO2/Si 150Ar 5
Na2MoO4 + S19 2H Nanosheet Monolayer 730–750 soda lime glass slide 80Ar 10–20
Na2MoO4 + ZnS42 2H Nanosheet Monolayer 780 Sapphire/SiO2/Si 100Ar 10–60
(NH4)2MoO4 + KI + S24 2H Film Monolayer 800 Sapphire Ar 10
MoSe2 (NH4)2MoO4 + KI + Se24 2H Film Monolayer 800 sapphire Ar/H2 10
Na2MoO4 + Se19 2H Nanosheet Monolayer 750–800 soda lime glass slide 80Ar/8 H2 10–20
Na2MoO4 + ZnSe42 2H Nanosheet Monolayer 800 Sapphire/SiO2/Si 100Ar 10–60
Na2MoO4 + Na2SeO320 2H Nanosheet Monolayer 775–850 SiO2/Si 190Ar/10H2 5–10
WS2 (NH4)10H2(W2O7)6 + S32 2H Nanosheet 1.5–2 nm 700 SiO2/Si 300Ar 14
Na2WO4·H2O + N2H4 + (CH3)2S243 2H Film 0.65 nm 850 SiO2/Si 350Ar 30
Na2WO4 + S19 2H Nanosheet Monolayer 730–780 soda lime glass slide 80Ar/4H2 10–20
Na2WO4 + ZnS42 2H Nanosheet Monolayer 930 Sapphire/SiO2/Si 100Ar 10–60
(NH4)2WO4 + KI + S24 2H Film Monolayer 850 sapphire Ar/H2 10
WSe2 Na2WO4 + ZnSe42 2H Nanosheet Monolayer 820 Sapphire/SiO2/Si 100Ar 10–60
(NH4)2WO4 + KI + Se24 2H Film Monolayer 850 sapphire Ar/H2 10
MoTe2 Na2MoO4 + Te19 1T’ Nanosheet   730–750 soda lime glass slide 120Ar/20H2; 10–20
(NH4)6Mo7O24·4H2O + C24H39NaO5 + Te27 1T’ Nanosheet 0.8 nm 700/500 SiO2/Si 400N2/25H2; 5
Na2MoO4 + ZnTe42 2H Nanosheet Monolayer 750–800 Sapphire/SiO2/Si 100Ar 10–60
Na2MoO4 + ZnTe42 1T’ Nanosheet Monolayer 800 Sapphire/SiO2/Si 100Ar 10–60
(NH4)6Mo7O24 + NaOH + Te44 1T’ Nanosheet 0.82 ± 0.04 nm 730 SiO2/Si 100Ar/3H2 15
WTe2 Na2WO4 + ZnTe42 1T’ Nanosheet Monolayer 780 Sapphire/SiO2/Si 100Ar 10–60
(NH4)6H2W12O40 + Te28 1T’ Nanosheet 0.8 nm 650 SiO2/Si N2/H2 6
Na2WO4 + Na2TeO320 1T’ Nanosheet 2.1 nm 775–825 sapphire 95Ar/5H2 5
NbSe2 C4H4NNbO9·xH2O + NaOH + Se21 2H Nanosheet 0.7 nm 800 SiO2/Si 600N2/15H2 20
ReSe2 NaReO4 + Na2SeO320 1T’ Nanosheet   750 sapphire 190Ar/10H2 5–10