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. Author manuscript; available in PMC: 2024 Oct 28.
Published in final edited form as: Chem Rev. 2023 Mar 7;123(14):8945–8987. doi: 10.1021/acs.chemrev.2c00814

Figure 13: Coexistence curve (blue) and percolation line (dashed and solid green) for a solution of associative polymers undergoing UCST-style phase separation coupled to percolation.

Figure 13:

The red lines are tie lines (see section 6.1) that connect coexisting dilute and dense phases. There are two critical temperatures, Tcs for the segregative transition and Tcp for the percolation transition. For temperatures below Tcs and above Tcp there is the formal possibility of phase separation without percolation. Whether this regime is accessible or not will depend on the gap between the two critical temperatures Tcs and Tcp.