TABLE 2.

¹H and ¹³C NMR chemical shifts of CSPsN‐1.

Monosaccharide units		Chemical shifts (ppm)
		C1/H1	C2/H2	C3/H3	C4/H4	C5/H5	C6/H6
A	→4)‐α‐D‐Glcp‐(1→	99.55–99.88/5.40	71.60/3.65	73.42/3.93	76.35/3.66	71.41/3.83	60.57/3.86
B	→4)‐β‐D‐Glcp‐(1→	95.88/4.64	74.13/3.23	70.08/3.48	75.86/3.83	74.26/3.64	60.42/3.65
D	α‐D‐Glcp‐(1→	101.98/5.06	72.98/3.61	74.56/3.94	73.34/3.43	70.10/3.74	60.93/3.83
E	β‐D‐Glcp‐(1→	96.01/4.66	73.42/3.25	76.07/3.74	74.68/3.58	73.42/3.61	62.48/3.87
F	→3,4)‐α‐D‐Glcp‐(1→	99.97/5.23	74.26/3.56	75.87/3.83	72.78/3.77	73.22/3.90	62.64/3.73
G	α‐D‐Galp‐(1→	101.60/5.07	73.17/3.77	70.18/4.18	69.37/4.05	72.44/3.71	n.d./3.93
I	→4,6)‐α‐D‐Glcp‐(1→	102.38/5.39	74.45/3.58	76.05/3.71	78.50/3.68	n.d./3.91	71.64/3.80
J	→3)‐α‐D‐Glcp‐(1→	98.18/4.96	74.34/3.57	80.79/3.96	n.d./4.05	n.d.	n.d.
K	α reducing Glcp	92.04, 92.23/5.22	69.50/3.55	72.58/3.70	69.78/3.29	n.d.	n.d.

Abbreviation: n.d., not detected.