Table 2.
Changes of fatty acid content in walnut oil before and after oxidation.
| Fatty acids | Time | HO (ug/mL) | ZO (ug/mL) | AC (ug/mL) | 35%-SO (ug/mL) | SP (ug/mL) | TBHQ (ug/mL) | BHA (ug/mL) | NMS (ug/mL) |
|---|---|---|---|---|---|---|---|---|---|
| C6:0 | Onset | 4.9 ± 0.1a | 8.1 ± 0.4cd | 4.6 ± 0.7a | 8.5 ± 3.3d | 5.5 ± 0.6b | 5.6 ± 0.6b | 6.5 ± 1.4bc | 4.7 ± 1.6a |
| End | 5.3 ± 0.5a | 8.5 ± 0.4d | 6.7 ± 0.6b | 8.2 ± 0.4 | 7.5 ± 2.5c | 5.7 ± 0.6a | 6.6 ± 0.6b | 7.7 ± 0.2c | |
| C8:0 | Onset | 5.3 ± 0.2a | 6.2 ± 0.1b | 5.2 ± 0.2a | 7.1 ± 2.1c | 5.6 ± 0.2a | 5.4 ± 0.1a | 6 ± 0.5b | 5 ± 0.4a |
| End | 5.4 ± 0.1a | 8.3 ± 0.4c | 6.1 ± 0.2b | 6.6 ± 0.1b | 6.7 ± 1.8b | 5.6 ± 0.4a | 5.8 ± 0.5a | 6.3 ± 0.3b | |
| C10:0 | Onset | 3.6 ± 0.1a | 4.5 ± 0.2b | 3.4 ± 0.1a | 4.3 ± 1b | 3.6 ± 0.1a | 3.6 ± 0.2a | 4 ± 0.4b | 3.4 ± 0.1a |
| End | 3.5 ± 0.1a | 4.5 ± 0.1c | 3.7 ± 0.2b | 3.8 ± 0.1b | 4.2 ± 1.1c | 3.5 ± 0.4a | 3.6 ± 0a | 3.8 ± 0.1ab | |
| C11:0 | Onset | 6.1 ± 0.1a | 6.1 ± 0.1a | 5.9 ± 0.1a | 7.6 ± 2c | 6.1 ± 0.2a | 6.2 ± 0a | 6.4 ± 0.4b | 6 ± 0.3ab |
| End | 6.1 ± 0.1a | 6.2 ± 0.1a | 6.2 ± 0.1a | 6.1 ± 0.1a | 6.7 ± 1.4b | 5.9 ± 0.2a | 6.3 ± 0.2b | 6.3 ± 0.1b | |
| C12:0 | Onset | 6.4 ± 0.2b | 7.6 ± 0.2c | 5.8 ± 0.3a | 7.4 ± 1.3c | 6.3 ± 0.2b | 6.8 ± 0.3b | 6.5 ± 0.9b | 6.4 ± 0.3b |
| End | 5.8 ± 0.1a | 7.8 ± 0.6c | 6.7 ± 0.5b | 6.7 ± 0.2b | 7.1 ± 0.8b | 6.2 ± 0.2a | 6.4 ± 0.4ab | 6.9 ± 0.3b | |
| C13:0 | Onset | 6.5 ± 0.1a | 6.1 ± 0.2a | 6.2 ± 0.1a | 7.8 ± 2.1b | 6.3 ± 0.1a | 6.5 ± 0.2a | 6.7 ± 0.4a | 6.4 ± 0.4a |
| End | 6.3 ± 0.1a | 6.3 ± 0.1a | 6.4 ± 0.3a | 6.3 ± 0.2a | 7.3 ± 1.6b | 6.3 ± 0.2a | 6.7 ± 0.2b | 6.6 ± 0.3a | |
| C14:0 | Onset | 60.4 ± 1.8c | 58.3 ± 3.8b | 56.8 ± 2.1b | 53.1 ± 2a | 56.9 ± 3.3b | 62.5 ± 4.8c | 60.7 ± 3.6c | 67.3 ± 10.3d |
| End | 50.5 ± 3.8a | 60.4 ± 4.9d | 63.2 ± 5.8e | 54.1 ± 1.7b | 64.2 ± 2.9e | 58.1 ± 4.5c | 58.2 ± 9.4c | 76.1 ± 2.3f | |
| C14:1 T | Onset | 514.2 ± 45.2c | 519.4 ± 98.5d | 449.8 ± 55.5a | 508.4 ± 4.6b | 529.9 ± 42.3f | 556.2 ± 55.5g | 523.7 ± 12.9e | 561.6 ± 7 h |
| End | 392.3 ± 40.8a | 586.3 ± 66.2e | 582.9 ± 100.8e | 492.3 ± 33.3b | 517.1 ± 53.1d | 585.2 ± 27.6e | 584 ± 21.1e | 508.1 ± 35.6c | |
| C14:1 | Onset | 8932.3 ± 663.2b | 8883.3 ± 2285.4b | 6812.4 ± 2210.1ab | 8321.7 ± 2467.4b | 8192.5 ± 1891.2b | 8344.6 ± 2015.4b | 4515.4 ± 2281.9a | 4251.4 ± 1482.9a |
| End | 5669.8 ± 204.7ab | 10506.7 ± 1057.8c | 9828.3 ± 2391.6bc | 8719.2 ± 777.1b | 7885.9 ± 2138b | 6850.5 ± 2130.5b | 3505.6 ± 1638.9a | 4856.6 ± 743.9ab | |
| C15:0 | Onset | 68.5 ± 2.1cd | 20.1 ± 0.5a | 62.3 ± 1.4cd | 47 ± 1b | 61.5 ± 3.9cd | 70 ± 4.7cd | 66.9 ± 3.3cd | 74.2 ± 11.9d |
| End | 56.8 ± 5.1cd | 20.4 ± 0.8a | 68.9 ± 6.2cd | 47.3 ± 1.5b | 70.8 ± 1.8cd | 64.7 ± 4.8cd | 64.8 ± 9.1cd | 82.7 ± 2.9d | |
| C15:1 T | Onset | 101.2 ± 12.3a | 120.8 ± 1ab | 132 ± 16.8bc | 153.1 ± 13.4cd | 142.7 ± 1.9b | 149 ± 7.4c | 174 ± 22.2d | 193.4 ± 7.8f |
| End | 118.3 ± 5.9a | 185.9 ± 48.3bc | 166.7 ± 26.7b | 137.9 ± 26.6b | 143.1 ± 15.3b | 196.6 ± 43bc | 225.5 ± 29.3c | 155.8 ± 22.4b | |
| C15:1 | Onset | 135.6 ± 11.3ab | 138.8 ± 18.6ab | 131 ± 13.3a | 142.9 ± 5.3ab | 147.9 ± 9.3ab | 153.8 ± 13.6bc | 149.7 ± 4ab | 163 ± 4.6d |
| End | 111.5 ± 6.9a | 163.1 ± 19.6b | 161.2 ± 22.5b | 139.7 ± 10.1b | 142 ± 15.7b | 169.3 ± 13.6b | 167.3 ± 12.9b | 146.9 ± 11.7b | |
| C16:0 | Onset | 23601.3 ± 744.1ab | 28142.3 ± 1477.4c | 21344.2 ± 950.4a | 20496.5 ± 2224.4a | 20567.3 ± 1806.1a | 23875.2 ± 2132.8ab | 22953.6 ± 1435.2a | 26136.9 ± 5291.9bc |
| End | 18505.8 ± 2033.1ab | 28469.7 ± 2333.3c | 23696.2 ± 2621ab | 21917.6 ± 1312.7a | 24561.2 ± 788.4ab | 21861.3 ± 2010.7a | 21620.4 ± 4564.6a | 30205.7 ± 1039.4c | |
| C16:1 T | Onset | 333.2 ± 43.1ab | 347.6 ± 57.3ab | 307.8 ± 35.9a | 345.5 ± 5.9ab | 361.1 ± 30.4b | 380.2 ± 34.1b | 362.4 ± 5.1ab | 391.6 ± 6.9b |
| End | 272.6 ± 24.9a | 405.1 ± 44.8b | 394.7 ± 64.8b | 342.5 ± 21.4ab | 351.3 ± 42.6ab | 398.3 ± 19.6b | 397.6 ± 15.8b | 353.1 ± 26.1ab | |
| C16:1 | Onset | 1103.2 ± 63.6c | 813.5 ± 97.3a | 1022.6 ± 43.7bc | 919.5 ± 48.8ab | 1080.1 ± 91.5bc | 1181.3 ± 101.8c | 1133.9 ± 51.7cd | 1275.9 ± 155.8d |
| End | 883.1 ± 88.5a | 883 ± 74.1a | 1210.6 ± 148.3ab | 945.2 ± 2.6a | 1158.8 ± 55.1ab | 1133.8 ± 74.7ab | 1162.2 ± 119.6ab | 1364.2 ± 35.3b | |
| C17:0 | Onset | 166.7 ± 4.8bc | 138.4 ± 6.6ab | 153.7 ± 2.1ab | 133.3 ± 7.3a | 148.1 ± 12.8ab | 169.6 ± 12.5bc | 163.5 ± 9.1bcd | 182.1 ± 31.7d |
| End | 137.3 ± 13.5a | 140.8 ± 11.5a | 167.2 ± 17.6b | 138.8 ± 6.2a | 173.7 ± 4.6 | 156.4 ± 11.3ab | 155.6 ± 23.7ab | 203.2 ± 5.8c | |
| C17:1 T | Onset | 163.6 ± 9.4a | 160.1 ± 27.2a | 141.1 ± 16.3a | 157.5 ± 15.9a | 162.6 ± 11.3a | 165.1 ± 14.3a | 145 ± 0.7a | 155.9 ± 13.2a |
| End | 126.1 ± 7.4a | 184 ± 14.8c | 174.7 ± 18.1b | 159.8 ± 9b | 156.4 ± 22.9ab | 172.9 ± 13.5bc | 147.9 ± 13.7ab | 144.6 ± 11.5ab | |
| C17:1 | Onset | 261.1 ± 14.2a | 235.5 ± 29.8a | 234.2 ± 17.9a | 233.2 ± 31.4a | 252 ± 14.3a | 257.7 ± 26.7a | 224.6 ± 22.9a | 237.3 ± 32.4a |
| End | 208.3 ± 13.1a | 266.8 ± 18.6bc | 275.8 ± 22c | 244.8 ± 7.7b | 255.8 ± 32.2b | 265.4 ± 30.8bc | 200.1 ± 21.5a | 248.3 ± 23.2b | |
| C18:0 | Onset | 6268.7 ± 174.6ab | 15,719 ± 802.8d | 5529.6 ± 115.3ab | 7438.2 ± 787c | 5290.3 ± 548.4a | 6147.5 ± 583.5abc | 5892.4 ± 370.3ab | 6779.7 ± 1445.5abc |
| End | 4882.6 ± 584.8a | 16149.3 ± 1486.9e | 6014.2 ± 678.4b | 8078.4 ± 379.6d | 6539.1 ± 101.8b | 5,600 ± 439.2a | 5619.2 ± 1072.6a | 7695.3 ± 244.2c | |
| C18:1 N12T | Onset | 113.5 ± 6.1a | 126.2 ± 21.2ab | 110.1 ± 6.5a | 125.5 ± 2.1ab | 130.3 ± 14.5ab | 134.6 ± 14.2ab | 139.3 ± 20.1ab | 153 ± 22.2b |
| End | 93.5 ± 6.4a | 141.2 ± 14.4b | 135.6 ± 30.9ab | 124 ± 7.6ab | 125.7 ± 4ab | 138.9 ± 14ab | 164.7 ± 15.2b | 140 ± 20.7ab | |
| C18:1 N9T | Onset | 194.7 ± 6.2a | 230.3 ± 29ab | 213.5 ± 8.5a | 229.8 ± 16ab | 244.4 ± 26.3abc | 267.9 ± 19.2c | 291.5 ± 41.4c | 322.6 ± 49.2d |
| End | 179.7 ± 21.2a | 248 ± 20.3b | 249.5 ± 59.5b | 227.2 ± 11.8b | 247.7 ± 4b | 268.4 ± 17.3b | 335.3 ± 10.6c | 279.7 ± 33.2bc | |
| C18:1 N7T | Onset | 315.1 ± 28.9a | 346.1 ± 47.3a | 288.4 ± 29.5a | 320 ± 7.4a | 334.3 ± 35.7a | 342.8 ± 34.4a | 306.9 ± 23.7a | 311.2 ± 45.5a |
| End | 256.4 ± 18.4a | 378.1 ± 34.9c | 361.8 ± 58.9c | 321.6 ± 18.1bc | 326.7 ± 35.9bc | 351.2 ± 12.6bc | 301.7 ± 25.8b | 314 ± 10.8b | |
| C18:1 N12 | Onset | 1265.9 ± 208.5a | 2303.1 ± 681.4a | 2800.5 ± 1544.9ab | 2671.2 ± 2367.5ab | 2669.8 ± 1603.3ab | 2889.4 ± 887.7ab | 3,489 ± 1635.1ab | 5322.3 ± 812.7b |
| End | 1320.9 ± 64.4a | 993.3 ± 212.5a | 2091.1 ± 1213.9ab | 1,191 ± 147.8a | 3090.3 ± 383.5b | 2453.7 ± 817.7ab | 5113.4 ± 1140.9c | 7258.4 ± 3381.1d | |
| C18:1 N9c | Onset | 38650.8 ± 1942.9a | 80728.6 ± 574.8c | 36216.1 ± 1412.7a | 46504.3 ± 4343.8b | 34740.7 ± 2217.8a | 40229.4 ± 3155.7ab | 40188.4 ± 2102.1ab | 46478.5 ± 8498.4b |
| End | 32074.9 ± 3529.8a | 78498.3 ± 3009.2c | 39953.2 ± 3527.3a | 49146.6 ± 2400.8b | 40849.1 ± 486.8a | 37811.9 ± 3787.7ab | 39509.1 ± 6182.9ab | 53486.7 ± 2593.5b | |
| C18:1 N7 | Onset | 3706.4 ± 195.3ab | 5156.5 ± 2883.5b | 3346.4 ± 80.6ab | 2916.4 ± 272a | 3326.7 ± 275.8ab | 3842.9 ± 410ab | 3723.4 ± 215.6ab | 4353.1 ± 907.9ab |
| End | 2941.7 ± 392.5a | 5214.3 ± 2677.8b | 3850.6 ± 403.5ab | 3133.3 ± 137a | 3963.8 ± 159.2ab | 3502.4 ± 313.3ab | 3564.2 ± 646.7ab | 4886.5 ± 211.9ab | |
| C18:2 N6T | Onset | 96.6 ± 8.2ab | 108.5 ± 13.5b | 87.4 ± 4.8a | 102.5 ± 1.2b | 103 ± 6.6b | 105.1 ± 9.2b | 101.1 ± 0.8b | 110.4 ± 4.7b |
| End | 84.6 ± 3.8a | 116.7 ± 8b | 107.2 ± 16.4b | 99.9 ± 5ab | 99.6 ± 6.3ab | 106.7 ± 6.1b | 108.8 ± 6.8b | 105.7 ± 7.8b | |
| C19:1 N12T | Onset | 110.2 ± 9.8a | 130 ± 8.2ab | 112.1 ± 1.2a | 113.3 ± 3.8a | 122.4 ± 35.4a | 121.8 ± 24.1ab | 110.3 ± 11.5a | 101.7 ± 14.5a |
| End | 104.6 ± 5ab | 151 ± 24.6c | 123.8 ± 40.4b | 105 ± 12.9ab | 102 ± 17.3a | 140.7 ± 5.8c | 99.3 ± 16.2a | 91.4 ± 18.9a | |
| C19:1 N9T | Onset | 46.1 ± 2.8ab | 60.9 ± 3b | 47.9 ± 1.9ab | 49.9 ± 4.4a | 47.7 ± 11.9abb | 45.9 ± 5.7ab | 47.6 ± 6.2ab | 43.4 ± 6.6a |
| End | 44.7 ± 6.5a | 62.2 ± 8.3b | 47.9 ± 10.1a | 45 ± 7.2a | 43.6 ± 8.2a | 55.8 ± 3.4ab | 43 ± 5.1a | 40.7 ± 7.5a | |
| C18:2 N6 | Onset | 119210.3 ± 3385.5ab | 110,880 ± 4524.4a | 122,005 ± 1630.2bc | 113700.2 ± 10086.5abc | 125,209 ± 5374.4b | 130993.5 ± 6867.1b | 133367.3 ± 4762.8c | 146724.8 ± 12270.7d |
| End | 116956.6 ± 8696a | 110735.8 ± 6984.1a | 132690.2 ± 5172.9bc | 118632.3 ± 3065abc | 123147.8 ± 1529.2b | 128985.4 ± 10929.2b | 138523.9 ± 9796c | 154891.7 ± 2179.4d | |
| C20:0 | Onset | 228 ± 13a | 1795.7 ± 111.9c | 206.2 ± 10.9a | 586.7 ± 59.7b | 199.5 ± 17.6a | 227.2 ± 20.8a | 225 ± 11.9a | 266.5 ± 52.5a |
| End | 181.8 ± 24.8a | 1776.4 ± 136.6c | 223.1 ± 22.7a | 633.3 ± 27.5b | 237.8 ± 7.7a | 215 ± 20.6a | 221.3 ± 40.3a | 299.2 ± 5.9a | |
| C18:3 N6 | Onset | 61.5 ± 5.6a | 58.2 ± 1.8a | 64.4 ± 8.1a | 59.2 ± 2.6a | 65.6 ± 5.6a | 86 ± 7.1ab | 88.7 ± 10.7ab | 123.1 ± 19.5c |
| End | 57.4 ± 4.3a | 59.8 ± 3.8a | 75.6 ± 18.1ab | 54.1 ± 1.1a | 78.8 ± 6.2ab | 88.9 ± 17.7b | 101.6 ± 16.1bc | 105.2 ± 19.6bc | |
| C20:1 T | Onset | 117.7 ± 11.9a | 119.8 ± 15.8a | 118.5 ± 5.7a | 121.3 ± 8.5a | 135.8 ± 5.5ab | 152.9 ± 12.1b | 171.2 ± 24.1b | 240.7 ± 13.2c |
| End | 104.2 ± 9.5a | 133 ± 8.3ab | 151.5 ± 29.5ab | 118.6 ± 4.4a | 133.2 ± 8.1ab | 173.5 ± 17.7b | 215.8 ± 1.2c | 191.2 ± 35.3b | |
| C20:1 | Onset | 10665.5 ± 434.4c | 558.3 ± 41.1a | 9917.4 ± 309.4c | 6136.9 ± 401b | 9658.5 ± 955.2c | 11257.7 ± 1216.6cd | 11064.4 ± 837.9cd | 12862.8 ± 2599.1d |
| End | 8620.9 ± 1012.9c | 582.8 ± 44.3a | 11094.5 ± 1176.7c | 6477.3 ± 396.4b | 11582.5 ± 169.6c | 10251.2 ± 1121.5cd | 10520.7 ± 2042cd | 14972.7 ± 560.1d | |
| C18:3 N3 | Onset | 31309.8 ± 1287.2ab | 909.3 ± 70.4a | 27794.9 ± 1381.2c | 17155.8 ± 2132.5b | 27842.5 ± 2208.1c | 31864.6 ± 2850.7cd | 31173.5 ± 1753.6cd | 36790.3 ± 7592.1e |
| End | 24389.4 ± 3698.1b | 905.5 ± 76.4a | 31606.4 ± 2531.9d | 18527.2 ± 1266.1b | 32815.1 ± 1210.8d | 28650.4 ± 2935.8c | 29088.7 ± 6196.3c | 42728.7 ± 2027.4e | |
| C21:0 | Onset | 42.1 ± 1.2a | 29.1 ± 1.5a | 37.6 ± 0.6a | 34.1 ± 1a | 36.4 ± 1.9a | 41.2 ± 3.1a | 39.8 ± 1.8a | 44.8 ± 7.4a |
| End | 35.3 ± 2.8a | 28.9 ± 1.7a | 39.8 ± 3.2a | 34 ± 1.7a | 43.4 ± 2.4ab | 37.6 ± 2.4a | 37.8 ± 4.6a | 50.1 ± 0.2b | |
| C20:2 | Onset | 126.4 ± 9.9a | 127 ± 8.2a | 113.5 ± 3.3a | 121.2 ± 8.4a | 124.2 ± 8a | 133.3 ± 12.5a | 126.1 ± 2a | 153.1 ± 23.1b |
| End | 109.6 ± 8.4a | 131.9 ± 6.8ab | 133.6 ± 12.3ab | 117.3 ± 3.3a | 128 ± 1.2ab | 129.7 ± 14.2ab | 132.9 ± 4.6ab | 160.7 ± 7.9c | |
| C22:0 | Onset | 67.7 ± 4.1a | 318.9 ± 15c | 62.1 ± 1.1a | 120.3 ± 9.7b | 59.4 ± 4.2a | 67.1 ± 5.7a | 65.7 ± 3.4a | 73.7 ± 12.9a |
| End | 56 ± 6.4a | 324.9 ± 26.7c | 65.6 ± 4.9a | 126.8 ± 6.6b | 73.5 ± 1.5a | 63.6 ± 5.1a | 63.2 ± 8.6a | 84.5 ± 1.2a | |
| C20:3 N6 | Onset | 96 ± 7.3a | 102.4 ± 13.3a | 100.3 ± 11.6a | 113.3 ± 16.6ab | 115.8 ± 10.5ab | 121.8 ± 13b | 109.7 ± 8.1ab | 110.4 ± 1.9ab |
| End | 86.4 ± 6.4a | 113 ± 12a | 131.9 ± 21b | 106.6 ± 4.7a | 111.9 ± 5.7a | 120.8 ± 2ab | 126.6 ± 16.1ab | 120.7 ± 2.2ab | |
| C22:1 N9T | Onset | 134.7 ± 12b | 131.7 ± 19.9b | 114.9 ± 9.4a | 132.4 ± 18.1b | 135.7 ± 7.2b | 145.7 ± 22.7b | 167.4 ± 20.8b | 178.4 ± 22.3c |
| End | 112.6 ± 11.3a | 151.1 ± 11.1b | 149 ± 21b | 127.8 ± 2.7a | 127.5 ± 14.6a | 150.3 ± 13.5b | 198.5 ± 31.3c | 177.8 ± 15.7bc | |
| C22:1 N9 | Onset | 85.1 ± 10.2b | 81.6 ± 15.9b | 60.7 ± 7.1a | 83 ± 14.9b | 81.8 ± 5.1b | 79.2 ± 14.3b | 61.9 ± 7.9a | 82.6 ± 11b |
| End | 67.8 ± 10.2a | 99.7 ± 8.2c | 82 ± 14b | 74.6 ± 2.4a | 69.6 ± 11.2a | 76.6 ± 16.1a | 75.5 ± 9.8a | 91.6 ± 6.2c | |
| C20:3 N3 | Onset | 22.9 ± 2.7a | 20.8 ± 2.8a | 18.1 ± 0.9a | 25.7 ± 0.9a | 21.9 ± 1.8a | 23.1 ± 3.7a | 21.8 ± 0.3a | 24.7 ± 3a |
| End | 22.3 ± 2a | 21.8 ± 0.7a | 25.1 ± 3.2a | 20.3 ± 0.9a | 23.1 ± 2.1a | 21.8 ± 5.6a | 23.8 ± 3.7a | 30.2 ± 0.8b | |
| C20:4 N6 | Onset | 35.4 ± 6.4b | 32.7 ± 3.2b | 24.9 ± 1.9a | 40.6 ± 1.2c | 33.6 ± 5.2b | 32.1 ± 5.6ab | 29.1 ± 1.7ab | 35.9 ± 5.9b |
| End | 34.1 ± 3.3a | 35.5 ± 1a | 33.7 ± 3.9a | 30.5 ± 3.2a | 30.1 ± 2.4a | 29.5 ± 10.3a | 33.1 ± 6.6a | 41.6 ± 2.7ab | |
| C23:0 | Onset | 30.6 ± 0.6a | 58.2 ± 2.3c | 28.6 ± 0.7a | 37.1 ± 1.4b | 28 ± 1.6a | 30.3 ± 3a | 30.4 ± 1.4a | 31.6 ± 4a |
| End | 27.5 ± 1a | 57.7 ± 3.7c | 30.5 ± 2.1a | 35.8 ± 1.4ab | 33 ± 2.4ab | 28.2 ± 1.9a | 29 ± 2.4a | 36.1 ± 1.2ab | |
| C22:2 | Onset | 48.7 ± 6a | 48.2 ± 5.6a | 44.4 ± 0.7a | 49.5 ± 7.6a | 52.5 ± 5ab | 55.6 ± 6.5ab | 52.9 ± 2.7ab | 63.8 ± 4.6b |
| End | 46.4 ± 4.4a | 53.9 ± 1.4ab | 55.2 ± 4.7ab | 46.8 ± 1.8a | 46.8 ± 3.8a | 54.9 ± 7.9ab | 65 ± 3b | 63.8 ± 6.2b | |
| C20:5 N3 | Onset | 26.7 ± 2.9a | 22.9 ± 2.2a | 19.5 ± 0.8a | 29.9 ± 6.6a | 24 ± 2.7a | 24.3 ± 3.2a | 30.4 ± 14.4a | 27.7 ± 4.5a |
| End | 23.7 ± 2.9a | 24.1 ± 1.1a | 24.1 ± 2.5a | 22.6 ± 1.4a | 28.5 ± 10.8ab | 23.7 ± 5.3a | 24.7 ± 4.1a | 27.2 ± 2.6ab | |
| C24:0 | Onset | 27 ± 1.3a | 174.9 ± 7.4c | 24 ± 0.4a | 61.5 ± 6.1b | 23.5 ± 1.4a | 25.8 ± 2a | 25.5 ± 2.1a | 26.7 ± 3.8a |
| End | 22.5 ± 1.9a | 179.6 ± 11.2c | 25.6 ± 2.1a | 65.8 ± 3.4b | 27.8 ± 0.8a | 24.2 ± 2a | 24.6 ± 1.8a | 30.2 ± 1.1a | |
| C24:1 | Onset | 407.7 ± 62.3c | 394.8 ± 54.9bc | 288.5 ± 13.6a | 358.1 ± 91.7bc | 381 ± 10.7bc | 363.6 ± 58.8bc | 323.8 ± 49.9b | 432.5 ± 35.6c |
| End | 339 ± 54a | 460.5 ± 27.7c | 370 ± 45.9a | 394.6 ± 10.9b | 328.4 ± 81.9a | 402.7 ± 45bc | 368.9 ± 39.2b | 392.5 ± 36.1b | |
| C22:4 | Onset | 33 ± 4.6c | 22.7 ± 2.6ab | 14.3 ± 1.2a | 23.7 ± 2.5ab | 22.9 ± 1.7ab | 21.7 ± 6.2ab | 18.4 ± 0.9a | 27.9 ± 5.3ab |
| End | 24.8 ± 6.7b | 25.5 ± 1.7b | 23.3 ± 4.3b | 20.4 ± 1.8a | 18.2 ± 1.9a | 19.4 ± 6a | 23.2 ± 6.8b | 38.9 ± 26.6c | |
| C22:5 N6 | Onset | 29.3 ± 5.6c | 20.8 ± 3b | 10.6 ± 1.1a | 23.4 ± 3.8b | 24.2 ± 6.3b | 18.7 ± 5.7ab | 15.1 ± 0.9ab | 24.5 ± 4.2bc |
| End | 23.6 ± 6b | 23.2 ± 1.2b | 19.5 ± 4ab | 17.4 ± 2.3a | 13.7 ± 1.5a | 16.4 ± 6.4a | 20.4 ± 8.4ab | 24.7 ± 3.2b | |
| C22:5 N3 | Onset | 24.7 ± 8.1c | 18 ± 1.7ab | 8.5 ± 0.2a | 21 ± 5.1b | 17.7 ± 3.5ab | 15 ± 4.9ab | 12.1 ± 1.7a | 19.5 ± 3.1ab |
| End | 23 ± 7b | 21.4 ± 2.3b | 15.7 ± 3.8a | 14.7 ± 2.2a | 12.4 ± 1.8a | 14.9 ± 5.4a | 16.8 ± 6.5a | 22.1 ± 3.8b | |
| C22:6 N3 | Onset | 29.6 ± 11.9c | 23.2 ± 4.7ab | 12.3 ± 1.2a | 27.6 ± 5.6bc | 21.4 ± 3.4b | 21.5 ± 7.5b | 17.1 ± 2.2a | 27.2 ± 2.5bc |
| End | 30.4 ± 9.2bc | 28 ± 2b | 26.5 ± 5.3b | 22 ± 2.8ab | 19.6 ± 0.7a | 21.4 ± 7.3a | 26.5 ± 9.3ab | 32.2 ± 4.2c |
The results are presented mean ± SD (n = 3). Different letters indicated that the difference between the groups was statistically significant (p < 0.05).