Reaction rate and photonic efficiency for the bromination of 6-chloro-3-methyluracil at Δt = 0–720 s concerning different reaction modules and reaction scales.
Entry | Reactor module | Reaction scale (g) | Reaction volume (mL) | Applied photon flux (μmol s−1) | % yield | Δt (s) | Rate (μmol s−1) | Photonic efficiency (ξext) |
---|---|---|---|---|---|---|---|---|
1 | 1XA | 0.96 | 10 | 46 | 94 | 0–720 | 6.2 | 0.13 |
2 | 2XA | 4.8 | 50 | 102 | 93 | 0–720 | 31 | 0.30 |
3 | 4XA | 9.6 | 100 | 185 | 94 | 0–720 | 62 | 0.34 |