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. 2024 Oct 11;10(20):e39109. doi: 10.1016/j.heliyon.2024.e39109

Table 5.

Residues (mg kg−1) of fipronil and its metabolites in chilli fruits at the lower dose (40 g a.i. ha−1).

Days Control Fipronil
Desulfinyl (MB046513)
Sulfide (MB045950)
Sulfone (MB046136)
Total
Meana± SD Meanb± SD Meanb± SD Meanb± SD
0 ND 0.574 ± 0.002 (0.0)a 0.123 ± 0.002 (0.0) 0.031 ± 0.002 (0.0) 0.180 ± 0.004 (0.0) 0.908 (0.0)
1 ND 0.380 ± 0.002 (33.8) 0.101 ± 0.002 (17.9) 0.019 ± 0.003 (38.7) 0.137 ± 0.003 (23.9) 0.637 (29.8)
3 ND 0.238 ± 0.016 (58.5) 0.074 ± 0.003 (39.8) 0.006 ± 0.001 (80.6) 0.066 ± 0.003 (63.3) 0.384 (57.7)
5 ND 0.182 ± 0.003 (68.3) 0.044 ± 0.002 (64.2) 0.002 ± 0.001 (93.5) 0.020 ± 0.001 (88.9) 0.248 (72.7)
7 ND 0.064 ± 0.003 (88.9) 0.015 ± 0.003 (87.8) BDL 0.006 ± 0.001 (96.7) 0.085 (90.6)
10 ND 0.023 ± 0.004 (96.1) BDL BDL 0.023 (97.5)
15 ND BDL BDL
Correlation Coefficient R2 = 0.974 Correlation Coefficient R2 = 0.937 Correlation Coefficient R2 = 0.998 Correlation Coefficient R2 = 0.985
Regression Equation y = -0.212x + 1.348
RL50 = 2.2
Waiting Period (Days) = 5
Regression eq. Log Y = −0.136x + 1.780 Regression Equation y = −0.123x + 1.156 Regression Equation y = -0.232x + 0.498
RL50 = 3.4 RL50 = 3.8 RL50 = 1.2
Waiting Period (Days) = 7 Waiting Period (Days) = 5 Waiting Period (Days) = 3
a

% reduction of four replications.

b

Mean of four replications BDL = Below Determination Level ND=Not Detected.