Figure 11.

Comparison of the experimental kinetic data (points) and the time courses calculated with the optimized microkinetic model, after adjusting the free energies of a, c-TS, and f-TS to obtain the best fit. (a) Experiments where [Ru-imine]₀ was varied with no added PCy₃. (b) Experiments where the hydrogen pressure was varied with no added PCy₃. (c) Experiments where [PCy₃]₀ was varied. (d) Experiments where [Ru-imine]₀ was varied with 60 mM added PCy₃. (e) Experiments where the hydrogen pressure was varied with 60 mM added PCy₃.