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Kinetics of Ru-imine hydrogenation with varying hydrogen pressure, with [PCy3]0 held constant at 60 mM. The top plot shows the evolution of [Ru-imine] over time, and the bottom-left plot shows the evolution of ln[Ru-imine] over time. The bottom-right plot shows the dependence of kobs on the hydrogen pressure. The kobs values (top right) are derived from the period between 85% and 98% conversion, as highlighted in the bottom-left plots.
