Table 2.
Kinetics for fipronil degradation in soil by FA.
Pesticide concentration (μg/g) | Soil Moisture (%) | Soil sterility | Isolate inoculation* | D (%) ± SD** | t1/2 (day)*** | R2**** | k***** ± SE (day−1) | k******(+/−) ± SE |
---|---|---|---|---|---|---|---|---|
15 | 100 | Sterile | + | 48.83f ± 1.91 | 16 | 0.91 | 0.044 ± 0.005 | 0.96 ± 0.11 |
− | 49.95ef ± 0.96 | 15 | 0.97 | 0.046 ± 0.002 | ||||
Non-sterile | + | 83.89a ± 1.51 | 5 | 0.99 | 0.127 ± 0.004 | 1.63 ± 0.08 | ||
− | 66.90c ± 2.09 | 9 | 0.96 | 0.078 ± 0.003 | ||||
20 | Sterile | + | 59.73cd ± 0.84 | 11 | 0.99 | 0.065 ± 0.001 | 12.10 ± 0.93 | |
− | 7.23i ± 0.68 | 129 | 0.89 | 0.005 ± 0.000 | ||||
Non-sterile | + | 56.11de ± 2.37 | 12 | 0.98 | 0.056 ± 0.002 | 1.91 ± 0.18 | ||
− | 33.33g ± 1.94 | 24 | 0.90 | 0.029 ± 0.003 | ||||
150 | 100 | Sterile | + | 43.42f ± 1.68 | 17 | 0.95 | 0.040 ± 0.006 | 3.01 ± 0.23 |
− | 17.53h ± 0.43 | 52 | 0.94 | 0.013 ± 0.001 | ||||
Non-sterile | + | 76.10b ± 3.51 | 6 | 0.98 | 0.119 ± 0.006 | 1.52 ± 0.08 | ||
− | 65.98c ± 1.91 | 9 | 0.99 | 0.078 ± 0.002 | ||||
20 | Sterile | + | 44.99f ± 2.63 | 16 | 0.91 | 0.043 ± 0.004 | 6.50 ± 0.67 | |
− | 8.93i ± 0.68 | 105 | 0.91 | 0.007 ± 0.000 | ||||
Non-sterile | + | 56.72de ± 0.91 | 11 | 0.94 | 0.063 ± 0.004 | 2.03 ± 0.23 | ||
− | 35.25g ± 3.45 | 22 | 0.98 | 0.031 ± 0.003 |
SE: Standard error (n = 3). SD: Standard deviation (n = 3).
+ and − indicate soils with and without isolate inoculation, respectively.
Degradation after 14 days. Values with the same lowercase superscript letters in the column do not defer significantly (Tukey’s HSD post hoc test, p = 0.05).
Half-lives of fipronil are calculated based on the first-order exponential decay model (Torabi et al., 2017).
The first-order exponential decay model coefficient of determination (Torabi et al., 2017).
Fipronil degradation rates based on the first-order exponential decay model (Torabi et al., 2017).
The contribution of FA to the degradation rates of fipronil (Equation 3). Standard errors are calculated via the error propagation method.