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Lipophilicity (a) of selected complexes (3Aq, 3Cl, and 3Br) expressed as log D7.4 measured via n-octanol/buffered aqueous solution partitioning at pH = 7.4 (HEPES buffer) in the absence of chloride ions, investigated over time (9, 25, 50, and 77 h). For better visualization, all the log D7.4 values are plotted against time in (b). The complexes were previously dissolved in the water phase (buffered). {ccomplex = 50 μM; T = 25.0 °C}.
