Table 2. Hydrogenation of Ketone Derivatives using Ru@SILP_GB under H₂ or H₂/CO2^a.

^aReaction conditions: Ru@SILP_GB (20 mg, 0.007 mmol Ru), substrate (0.25 mmol, 35 equiv), 1,4-dioxane (1 mL), 16 h, X = conversion, Y = yield. Conversions and product yields determined by GC-FID using tetradecane as the internal standard.

^bRest = corresponding byproduct formed by the dehydration of saturated alcohol.

^cRest = saturated alcohol products. Isolated yields are given in parentheses and the NMR spectra of isolated products are provided in Figures S28–S43.