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. 2024 Oct 22;146(44):30332–30339. doi: 10.1021/jacs.4c10217

Table 1. Summary of Photoswitching Properties for Cages and Azobenzene Subunits in This Study.

  Tetratopic
Ditopic
  A1 ACC-1 A2 ACC-2
Best EZ PSS 65% cis 77% cis 80% cis 54% cis
Best ZE PSS 13% cis 6% cis 6% cis 3% cis
t1/2 (25 °C)/h 220 ± 70 110 ± 10 4.78 ± 0.01 6.0 ± 0.1
ΔH/kJ mol–1 102 ± 7 104 ± 2 107 ± 8 83 ± 2
ΔS/J K–1 mol–1 -20 ± 20 -7 ± 6 30 ± 30 -51 ± 7