Table 13.
Sample | Investigated Parameter | Concentration Range | Chemometrics Data | Ref. | ||||
---|---|---|---|---|---|---|---|---|
Pre-Processing, Regression | R2 | Root Mean Square Error | ||||||
Apple | Soluble solid content—SSC, % | 11.0–14.0 | GA | 0.911 | 0.251 | [310] | ||
7.63–18.60 | SNV, MSC, CARS-PLS | 0.971 | 0.429 | [313] | ||||
8.00–13.60 | SGS, 2nd der., CARS-SPA-PLS | 0.850 | 0.443 | [318] | ||||
11.0–17.0 | SGS, 1st der., SPA, MNLR | 0.953 | 0.754 | [323] | ||||
7.8–24.1 | SNV, LS-SVM | 0.73 | 0.7 | [328] | ||||
9.13–15.66 | CARS/PLS | 0.9402 | 0.5079 | [329] | ||||
Complex model with pear | 11.1–15.2 | 2nd der., PLS | 0.88 | 0.43 | [332] | |||
Complex model with pear and peach | 10.20–15.60 | SPA-MWPLS | 0.96 | 0.46 | [333] | |||
MLR | 0.96 | 0.46 | ||||||
Titratable acidity—TA, % | 0.9–28.4 | SNV, LS-SVM | 0.68 | 0.89 | [328] | |||
Firmness, kg/cm2 | 1.5–12.7 | SNV, LS-SVM | 0.74 | 0.99 | ||||
Starch-Iodine Index | 2–10 | SNV, LS-SVM | 0.73 | 0.84 | ||||
Visual ripeness index, VRPI | n.i. | LS-SVR | 0.925 | 0.168 | [324] | |||
RPI | n.i. | PLS | 0.777 | 0.191 | ||||
IQI | n.i. | PLS | 0.951 | 0.291 | ||||
Streif index | n.i. | PLS | 0.768 | 0.082 | ||||
α-farnese, μmol/m2 | 15–1816 | NCL, PLS | 0.81–0.92 | 139 | [327] | |||
CTols | CT258 | 14–502 | 1st der. BCAP, PLS | 0.90; 0.94 | 59–60 | |||
CT281 | 1–450 | 0.91; 0.78 | ||||||
Maturity estimation | SSC, TA, firmness, anthocyanin | SGS, SNV, MSC, SLS, 1st der. 2nd der. PLS, PCR, SMLR, GA-PLS |
0.22–0.97 | n.i. | [319] | |||
Internal flesh browning | 93 good, 203 defect | PLS | 0.83 | 0.63 | [314] | |||
Sunscald | 161 shaded and sun-exposed 100 mild sun damaged |
MSC, 2nd der., PLS, iPLS-DA | 0.454 0.594- |
0.211 0.317 |
[317] | |||
Classification | Internal flesh browning | LDA | accuracy >95% | [314] | ||||
Damage | Bruise, Mouldy core Sunburn Internal browning |
PLS-DA, SPA-PLS, SELFS, iPLS-DA LDA |
accuracy > 90%; 92% R2cv = 0.59 accuracy 90% |
[336] | ||||
Maturation level—colour | ANN/SA | accuracy 100% | [331] | |||||
Variety; Freshness; Variety, freshness | PCA, VIP, PLS-DA | misclassification 0%; 5.8%; 2.0–3.9% | [335] | |||||
Bitter bit (BP) | 269 BP 719 non BP |
PLS-DA | accuracy 60–80% | [337] | ||||
Origin | TCA, LS-SVM | accuracy 90.91% | [339] | |||||
Fungal infection | SNV, CARS, SPA, KNN, LDA, LS/SVM, RF | accuracy 98.75% | [138] | |||||
Pear | Soluble solid content—SSC, % | 8.6–13.8 | PLS | 0.912 | 0.662 | [311] | ||
8.6–11.3 | SGS, SNV, 1st der., var.sel. PLS | 0.58 | 0.65 | [312] | ||||
10.8–14.6 | SGS, PLS | 0.92 | 0.41 | [315] | ||||
8.6–13.6- | aver. spectra, FWs PLS | 0.8611 | 0.6314 | [316] | ||||
9.8–16.8 | SGS, MSC, siPLS | 0.9657 | 0.2265 | [320] | ||||
13.4–16.9 | PCA, Si-GA-PLS, | 0.9406 | 0.165 | [321] | ||||
7.20–19.5 | SpectraNet–32 | 0.58 | 1.08 | [322] | ||||
8.2–16.5 | SNV, 2nd der., SVM | 0.71 | 0.7 | [338] | ||||
11.3–18.5 | OSC-PLS | 0.85 | 0.46 | [374] | ||||
11.3–18.5 | OSC-MLR | 0.86 | 0.46 | |||||
6 cultivars | 10.2–25.0 | Grad-CAM, SVR, CNN | n.i. | 0.33–1.64 | [326] | |||
Complex model with apple | 9.2–13.8 | 2nd der., PLS | 0.88 | 0.43 | [332] | |||
Complex model with apple and peach | 10.90–16.90 | SPA-MWPLS, MLR | 0.96 0.96 |
0.46 0.46 |
[333] | |||
Dry matter | 11.4–21.8 | SGS, SNV, 1st der., var.sel. PLS | 0.65 | 1.06 | [312] | |||
Firmness | 4.2–11.3 | PLS | 0.854 | 1.232 | [311] | |||
28.4–127.1 | PCA, Si-GA-PLS, | 0.9119 | 5.5003 | [321] | ||||
5.0–71.0 | SNV, SVM | 0.68 | 7.66 | [338] | ||||
15.00–35.86 | PLS | 0.58–0.845 | 2.65–3.98 | [325] | ||||
1.9–71.2 | OSC-PLS | 0.68 | 8.18 | [374] | ||||
1.9–71.2 | OSC-MLR | 0.56 | 9.28 | |||||
Maturity estimation | SSC, firmness, lignin cont. | SGS, SNV, MSC, OSC, 1st der., 2nd der., siPLS, UVE, MS-UVE-SPA, PLS, MLR, LSSVM, NIPALS | 0.61–0.96 | n.i. | [319] | |||
Classification | internal browning | PLS-DA | sensitivity 76% | [338] | ||||
Insect-affect | SGS CBAM-CNN |
accuracy 92.71% | [340] |