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. 2024 Oct 26;17(21):5224. doi: 10.3390/ma17215224
List of Abbreviations (In Order of Appearance)
YSZ yttria-stabilized zirconia
CGO10 Ce0.9Gd0.1O2−δ
CGO20 Ce0.8Gd0.2O2−δ
GDC Ce0.8Gd0.2O1.9
ScCeSZ Sc0.1Ce0.01Zr0.89O1.91
ScYbSZ Sc0.09Yb0.01Zr0.9O1.95
XRD X-ray diffraction spectroscopy
EDS energy-dispersive X-ray spectroscopy
EIS electrochemical impedance spectroscopy
SOFC solid oxide fuel cell
List of Symbols (In Order of Appearance)
Zr4+ zirconium cation
MeO metal in the second oxidation state oxide
MeZr zirconia in the fourth oxidation state ion sitting on metal in the second oxidation state lattice site with double positive charge
V0 double positively charged oxygen vacancy
O0x an oxygen ion sitting on lattice site with neutral charge
Me2O3 metal in the third oxidation state oxide
Re2O3 a rare earth oxide
Ce4+ ceria cation in the fourth oxidation state
Ce3+ ceria cation in the third oxidation state
δ oxygen deficiency in metal-doped oxide ceramic
X Vegard’s Slope
ri difference between the ionic radii of the dopant metal and Ce4+ for the coordination number equal to 8
zi charge difference between the introduced ion and Ce4+ ions
σ specific conductivity
2Θ angle between incident beam and the crystallographic reflection plane in XRD
A lattice constant
R1, R2, R3 resistor elements
CPE1, CPE2, CPE3 constant phase elements
L1 inductance element
R1, R2, R3 resistance parameters of resistors
CPE1-T, CPE2-T, CPE3-T time parameter in constant phase elements
CPE1-P, CPE2-T, CPE3-T phase parameter in constant phase element
L inductance element parameter
Z real impedance component
Z imaginary impedance component
Y real admittance component
Y imaginary admittance component
T absolute temperature
t temperature in degrees Celsius
q valency of mobile ions
c relative concentration of mobile ions to the number of possible positions in the lattice
μ mobility of the ions
e electron
V0n n-time negatively charged oxygen vacancy
O2− oxygen anion
A a constant in Arrhenius law
EA the activation energy for conduction
k Boltzman’s constant
PO oxygen partial pressure
m a parameter determined by both the type of the carrier (n or p) and the defects (e.g., oxygen vacancy) in the semiconductor
(OH) hydroxide ion
n numbers of electrons
Hi proton in interstitial site
(OH)O hydroxide ion sitting on oxygen lattice site with positive charge
List of Chemical Formulas (In Order of Appearance)
Ce0.8Gd0.2O1.9 assumed composition of commercial material (specimen GDC)
Sc0.1Ce0.01Zr0.89O1.95 assumed composition of commercial material (specimen ScCeSZ)
Sc0.09Yb0.01Zr0.9O1.95 assumed composition of commercial material (specimen ScYbSZ)
Ce(Re)O2−δ rare earth doped ceria
NH3 gaseous ammonia
H2 gaseous hydrogen
ZrO2 zirconia
CO carbon monoxide
SiO2 silica
MnO2 manganese oxide
Al2O3 aluminum oxide
CaO calcium oxide
MgO magnesium oxide
Y2O3 ytrria
Sc2O3 scandia
Yb2O3 ytterbium oxide
Si3N4 a silicon nitride
AlN aluminum nitride
CuO copper (II) oxide
c-ZrO2 cubic zirconia
N2O nitrous oxide
H2O water