|
List of Abbreviations (In Order of Appearance)
|
| YSZ |
yttria-stabilized zirconia |
| CGO10 |
Ce0.9Gd0.1O2−δ
|
| CGO20 |
Ce0.8Gd0.2O2−δ
|
| GDC |
Ce0.8Gd0.2O1.9
|
| ScCeSZ |
Sc0.1Ce0.01Zr0.89O1.91
|
| ScYbSZ |
Sc0.09Yb0.01Zr0.9O1.95
|
| XRD |
X-ray diffraction spectroscopy |
| EDS |
energy-dispersive X-ray spectroscopy |
| EIS |
electrochemical impedance spectroscopy |
| SOFC |
solid oxide fuel cell |
|
List of Symbols (In Order of Appearance)
|
| Zr4+
|
zirconium cation |
|
MeO
|
metal in the second oxidation state oxide |
|
|
zirconia in the fourth oxidation state ion sitting on metal in the second oxidation state lattice site with double positive charge |
|
|
double positively charged oxygen vacancy |
|
|
an oxygen ion sitting on lattice site with neutral charge |
|
|
metal in the third oxidation state oxide |
|
|
a rare earth oxide |
| Ce4+
|
ceria cation in the fourth oxidation state |
| Ce3+
|
ceria cation in the third oxidation state |
|
δ
|
oxygen deficiency in metal-doped oxide ceramic |
|
X
|
Vegard’s Slope |
|
ri
|
difference between the ionic radii of the dopant metal and Ce4+ for the coordination number equal to 8 |
|
zi
|
charge difference between the introduced ion and Ce4+ ions |
|
σ
|
specific conductivity |
| 2Θ
|
angle between incident beam and the crystallographic reflection plane in XRD |
|
A
|
lattice constant |
| R1, R2, R3 |
resistor elements |
| CPE1, CPE2, CPE3 |
constant phase elements |
| L1 |
inductance element |
|
R1, R2, R3 |
resistance parameters of resistors |
|
CPE1-T, CPE2-T, CPE3-T
|
time parameter in constant phase elements |
|
CPE1-P, CPE2-T, CPE3-T
|
phase parameter in constant phase element |
|
L
|
inductance element parameter |
|
Z′ |
real impedance component |
|
Z″ |
imaginary impedance component |
|
Y′ |
real admittance component |
|
Y″ |
imaginary admittance component |
|
T
|
absolute temperature |
|
t
|
temperature in degrees Celsius |
|
q
|
valency of mobile ions |
|
c
|
relative concentration of mobile ions to the number of possible positions in the lattice |
|
μ
|
mobility of the ions |
|
|
electron |
|
|
n-time negatively charged oxygen vacancy |
| O2−
|
oxygen anion |
|
A
|
a constant in Arrhenius law |
|
EA
|
the activation energy for conduction |
| k |
Boltzman’s constant |
|
|
oxygen partial pressure |
|
m
|
a parameter determined by both the type of the carrier (n or p) and the defects (e.g., oxygen vacancy) in the semiconductor |
|
|
hydroxide ion |
|
n
|
numbers of electrons |
|
|
proton in interstitial site |
|
|
hydroxide ion sitting on oxygen lattice site with positive charge |
|
List of Chemical Formulas (In Order of Appearance)
|
| Ce0.8Gd0.2O1.9
|
assumed composition of commercial material (specimen GDC) |
| Sc0.1Ce0.01Zr0.89O1.95
|
assumed composition of commercial material (specimen ScCeSZ) |
| Sc0.09Yb0.01Zr0.9O1.95
|
assumed composition of commercial material (specimen ScYbSZ) |
| Ce(Re)O2−δ
|
rare earth doped ceria |
| NH3
|
gaseous ammonia |
| H2
|
gaseous hydrogen |
| ZrO2
|
zirconia |
| CO |
carbon monoxide |
| SiO2
|
silica |
| MnO2
|
manganese oxide |
| Al2O3
|
aluminum oxide |
| CaO |
calcium oxide |
| MgO |
magnesium oxide |
| Y2O3
|
ytrria |
| Sc2O3
|
scandia |
| Yb2O3
|
ytterbium oxide |
| Si3N4
|
a silicon nitride |
| AlN |
aluminum nitride |
| CuO |
copper (II) oxide |
| c-ZrO2
|
cubic zirconia |
| N2O |
nitrous oxide |
| H2O |
water |