Table 2.
Compd. | λmax/nm (ε/104 M−1 cm−1) |
Φ oc | Φ co | λPL | Φ f | Solvent | Ref. |
---|---|---|---|---|---|---|---|
8o | 372 (6.33) | 0.34 | 466 | 0.1941 | CHCl3 | [25] | |
8c | 516 (2.57) | 0.02 | - | - | CHCl3 | [25] | |
8o+H+ | 378 | - | 476 | 0.0644 | CHCl3 | [25] | |
8c+H+ | 749 (0.68); 754 (0.67); 751 (0.22) | - | - | - | CHCl3 | [25] | |
9o | 375 (5.62) | 0.30 | 433 | 0.0973 | THF | [26] | |
9c | 518 (2.56) | 0.01 | - | - | THF | [26] | |
10o | 374 (4.68) | 0.40 | 436 | 0.0767 | THF | [26] | |
10c | 517 (1.86) | 0.02 | - | - | THF | [26] |
λmax: absorption maximum; ε: molar absorption coefficient; Φoc: cyclization quantum yield; Φco: cycloreversion quantum yield; λPL: fluorescence maximum; Φf: fluorescence quantum yield.