Table 5.
Compd. | λmax/nm (ε/104 M−1 cm−1) |
Φoc | Φco | Φf | τf(ns) | Solvent | Ref. |
---|---|---|---|---|---|---|---|
23o | 354 (10.64) | 0.31 | 0.002 | THF | [30] | ||
24o | 305 (3.91) | 0.094 | 0.006 | hexane | [31] | ||
25o | 354 (10.64) | 0.04 | 1.0 × 10−3 | 0.93 | 4.2 | CCl4 | [32] |
26o | - | 0.40 | 0.006 | 0.97 | 3.6 | CCl4 | [34] |
27o | - | 0.34 | 1.5 × 10−3 | - | - | EtOAc | [36] |
28o | - | 0.35 | 7.8 × 10−3 | - | - | EtOAc | [36] |
29o | - | 0.34 | 1.2 × 10−3 | - | - | EtOAc | [36] |
30o | - | 0.35 | 3.9 × 10−3 | - | - | EtOAc | [36] |
λmax: absorption maximum; ε: molar absorption coefficient; Φoc: cyclization quantum yield; Φco: cycloreversion quantum yield; Φf: fluorescence quantum yield; τf: fluorescence lifetime.