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. 2024 Nov 3;29(21):5202. doi: 10.3390/molecules29215202

Table 8.

Photophysical and photochemical parameters of 44o49o in benzene solution.

Compd. λmax/nm
(ε/104 M−1 cm−1)
λem/nm Φ oc Φ co Conversion Yield (%) Φf Solvent Ref.
44o 385 (0.59) 523 0.50 0.10 88 0.064 benzene [45]
45o 333 (0.81), 410 (0.699) 543 0.87 0.44 51 0.032 benzene [45]
46o 327 (0.792), 414 (0.975) 542 0.77 0.43 85 0.048 benzene [45]
47o 310 (2.75), 419 (0.954) 562 0.35 0.042 78 0.011 benzene [45]
48o 342 (0.656), 421 (1.64) 552 0.23 0.084 83 0.056 benzene [45]
49o 310 (2.17), 411 (3.61) 645 0.35 0.087 84 0.006 benzene [45]

λmax: absorption maximum; ε: molar absorption coefficient; Φoc: cyclization quantum yield; Φco: cycloreversion quantum yield; conversion yield: conversion ratio from open form to closed from at PSS state; Φf: fluorescence quantum yield.