Table 8.
Compd. | λmax/nm (ε/104 M−1 cm−1) |
λem/nm | Φ oc | Φ co | Conversion Yield (%) | Φf | Solvent | Ref. |
---|---|---|---|---|---|---|---|---|
44o | 385 (0.59) | 523 | 0.50 | 0.10 | 88 | 0.064 | benzene | [45] |
45o | 333 (0.81), 410 (0.699) | 543 | 0.87 | 0.44 | 51 | 0.032 | benzene | [45] |
46o | 327 (0.792), 414 (0.975) | 542 | 0.77 | 0.43 | 85 | 0.048 | benzene | [45] |
47o | 310 (2.75), 419 (0.954) | 562 | 0.35 | 0.042 | 78 | 0.011 | benzene | [45] |
48o | 342 (0.656), 421 (1.64) | 552 | 0.23 | 0.084 | 83 | 0.056 | benzene | [45] |
49o | 310 (2.17), 411 (3.61) | 645 | 0.35 | 0.087 | 84 | 0.006 | benzene | [45] |
λmax: absorption maximum; ε: molar absorption coefficient; Φoc: cyclization quantum yield; Φco: cycloreversion quantum yield; conversion yield: conversion ratio from open form to closed from at PSS state; Φf: fluorescence quantum yield.