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. 2024 Nov 3;29(21):5202. doi: 10.3390/molecules29215202

Table 10.

Photophysical and photochemical parameters of 61o68o in benzene solution.

Compd. λmax/nm
(ε/104 M−1 cm−1)
λem/nm Φ oc Φ co Φf τf (ns) Solvent Ref.
61o 295 (0.69), 402 (2.87) 496 - - 0.007 2.09 benzene [52]
62o 292(0.61), 399 (2.76) 478 0.022 0.012 0.247 1.00 benzene [52]
63o 292 (0.86), 393 (3.30) 473 0.012 0.009 0.097 0.59 benzene [52]
64o 292 (0.90), 397 (3.31) 468 0.027 0.016 0.262 1.03 benzene [52]
65o 295 (0.52), 424 (2.18) 543 0.005 0.004 0.014 < 0.5 benzene [52]
66o 291 (0.76), 417 (2.85) 522 0.025 0.005 0.178 1.52 benzene [52]
67o 293 (0.75), 416 (2.47) 506 0.018 0.002 0.585 2.63 benzene [52]
68o 295 (0.61), 420 (2.37) 505 0.038 0.014 0.556 2.27 benzene [52]

λmax: absorption maximum; ε: molar absorption coefficient; λem: fluorescence maximum; Φoc: cyclization quantum yield; Φco: cycloreversion quantum yield; Φf: fluorescence quantum yield; τf: fluorescence lifetime.