Table 10.
Compd. | λmax/nm (ε/104 M−1 cm−1) |
λem/nm | Φ oc | Φ co | Φf | τf (ns) | Solvent | Ref. |
---|---|---|---|---|---|---|---|---|
61o | 295 (0.69), 402 (2.87) | 496 | - | - | 0.007 | 2.09 | benzene | [52] |
62o | 292(0.61), 399 (2.76) | 478 | 0.022 | 0.012 | 0.247 | 1.00 | benzene | [52] |
63o | 292 (0.86), 393 (3.30) | 473 | 0.012 | 0.009 | 0.097 | 0.59 | benzene | [52] |
64o | 292 (0.90), 397 (3.31) | 468 | 0.027 | 0.016 | 0.262 | 1.03 | benzene | [52] |
65o | 295 (0.52), 424 (2.18) | 543 | 0.005 | 0.004 | 0.014 | < 0.5 | benzene | [52] |
66o | 291 (0.76), 417 (2.85) | 522 | 0.025 | 0.005 | 0.178 | 1.52 | benzene | [52] |
67o | 293 (0.75), 416 (2.47) | 506 | 0.018 | 0.002 | 0.585 | 2.63 | benzene | [52] |
68o | 295 (0.61), 420 (2.37) | 505 | 0.038 | 0.014 | 0.556 | 2.27 | benzene | [52] |
λmax: absorption maximum; ε: molar absorption coefficient; λem: fluorescence maximum; Φoc: cyclization quantum yield; Φco: cycloreversion quantum yield; Φf: fluorescence quantum yield; τf: fluorescence lifetime.