Table 2. Effect of Radical Scavengers on the Oxidation of Isobutane over La0.8Sr0.2FeO3−δa.
| entry | radical scavenger | total yield (%) | selectivity (%) | ||
|---|---|---|---|---|---|
| t-BuOH | TBHP | acetone | |||
| 1 | none | 31 | 71 | 7 | 19 |
| 2 | BHT | <1 | |||
| 3 | TEMPO | <1 | |||
| 4 | p-benzoquinone | <1 | |||
| 5 | 2-propanol | 3 | <1 | <1 | >99 |
Reaction conditions: La0.8Sr0.2FeO3−δ (0.1 g), isobutane (0.2 MPa, 3.2 mmol), radical scavenger (1 mmol), O2 (0.25 MPa), and PhCF3 (2 mL), 110 °C, 24 h.
