1H NMR, and 13C NMR data of compound (1 and 2) in CDCl3.
Compound 1 | Compound 2 | ||||
---|---|---|---|---|---|
Position | δ H | δ C | Position | δ H | δ C |
1 | 3.43, m | 71.2 | |||
2 | 2.92, 2.99, dd | 47.1 | 3 | 1.48, 1.23, m | 30.6 |
3 | 197.5 | 4 | 1.27,0.99, m | 36.3 | |
4 | 107.8 | 5 | 2.16,1.86, dd | 38.3 | |
5 | 160.1 | 6 | 138.4 | ||
6 | 110.2 | 7 | 5.23, d | 116.4 | |
7 | 141.2 | 8 | 5.23, d | 116.7 | |
8 | 6.90, s | 99.2 | 9 | 139.6 | |
9 | 153.4 | 10 | 1.88, m | 52.1 | |
11 | 6.73, s | 104.1 | 11 | 1.49, 1.40, m | 21.1 |
12 | 165.4 | 12 | 1.88, m | 25.6 | |
13 | 103.1 | 13 | 1.08, m | 54.5 | |
14 | 150.6 | 14 | 1.96, m | 38.8 | |
16-CH3 | 1.42, s | 27.5 | 15 | 5.11, m | 131.4 |
18-OCH3 | 3.80, s | 55.2 | 16 | 5.1, m | 129.5 |
20-OCH3 | 4.00, s | 61.63 | 17 | 1.88, m | 38.5 |
21-OH | 14.21 | 18 | 0.85, s | 18.2 | |
22-OH | 5.60 | 19 | 1.49, m | 31.23 | |
23 | 100.5 | 20 | 0.98, m | 19.5 | |
24 | 2.92,2.99, dd | 47.1 | 21 | 0.98 | 19.1 |
25 | 197.5 | 22 | 0.84, s | 19.3 | |
26 | 108.3 | 23 | 41.7 | ||
27 | 158.8 | 24 | 1.03, m | 13.5 | |
28 | 111.3 | 25 | 1.15, m | 37.3 | |
29 | 136.5 | 26 | 0.89, m | 19.3 | |
30 | 112.6 | 27 | 1.79, m | 43.6 | |
31 | 155.8 | 28 | 34.7 | ||
33 | 6.43, s | 97.2 | 29 | 0.93, s | 14.6 |
34 | 163.7 | ||||
35 | 6.21, s | 96.2 | |||
36 | 160.6 | ||||
38-CH3 | 1.52, s | 27.5 | |||
40-OCH3 | 3.99, s | 56.2 | |||
42-OCH3 | 3.81, s | 55.9 | |||
43-OH | 14.56 | ||||
44-OH | 7.12 |