| carbonate |
Am3+ + CO32– = [AmCO3]+
|
log β11 = 5.97 |
I = 0.1–0.3 M (NaClO4), T = 25 °C |
(55) |
| Am3+ + 2 CO32– = [Am(CO3)2]−
|
log β12 = 9.58 |
| [Am2(CO3)3](s) =
2 Am3+ + 3 CO32–
|
log Ksp = −29.70 |
| [Cm(CO3)2]− + CO32– = [Cm(CO3)3]2–
|
log K3 =
2.01 |
I = 3 M (NaClO4), T = 25 °C |
(57) |
| phosphate |
Ac3+ + H2PO4– = [AcH2PO4]2+
|
log K = 1.85 |
I = 0, T = 30 °C |
(78) |
| Am3+ + H2PO4– =
[AmH2PO4]2+
|
log K = 2.13 |
I = 0, T = 30 °C |
(79) |
| Am3+ + HPO42– = [AmHPO4]+
|
log K = 4.14 |
| Cm3+ + 2 H+ + PO43– = [CmH2PO4]2+
|
log
β121 = 22.02 |
I = 0.1 M (NaClO4), T = 24 °C |
(80) |
| Cm3+ + H+ + PO43– = [CmHPO4]+
|
log β111 = 18.56 |
| Cm3+ + H3PO4 = [CmH2PO4]2+ + H+
|
log K = −0.14 |
I = 1.1 M (NaClO4), T = 25 °C |
(81) |
| oxalate |
Ac3+ + C2O42– = [AcC2O4]+
|
log β11 = 3.56 |
I = 1 M (NaClO4), T = 25 °C |
(82) |
| Ac3+ + 2 C2O42– = [Ac(C2O4)2]−
|
log β12 = 6.16 |
| Am3+ + C2O42– = [AmC2O4]+
|
log β11 = 4.63 |
I = 1 M (NaClO4), T = 25 °C |
(82) |
| Am3+ + 2 C2O42– = [Am(C2O4)2]−
|
log β12 = 8.35 |
| Am3+ + 3 C2O42– = [Am(C2O4)3]3–
|
log β13 = 11.15 |
| Am3+ + C2O42– = [AmC2O4]+
|
log β11 = 5.34 |
I = 0.1 M (NaClO4), T = 23–26 °C |
(62) |
| Am3+ + 2 C2O42– = [Am(C2O4)2]−
|
log β12 = 9.14 |
| Am3+ + 3 C2O42– = [Am(C2O4)3]3–
|
log β13 = 11.49 |
| acetate |
Cm3+ + Acetate– = [CmAcetate]2+
|
log β11 = 3.18 |
I = 0, T = 20 °C |
(83) |
| Cm3+ + 2 Acetate– = [Cm(Acetate)2]+
|
log β12 = 4.80 |
| Cm3+ + 3 Acetate– =
[Cm(Acetate)3] |
log β13 =
5.19 |
| malonate |
Cm3+ + Malonate2– = [CmMalonate]+
|
log β11 = 5.26 |
I = 0, T = 20 °C |
(84) |
| Cm3+ + 2 Malonate2– = [Cm(Malonate)2]−
|
log
β12 = 8.38 |
| propionate |
Cm3+ + Propionate2– = [CmPropionate]2+
|
log β11 = 3.24 |
I = 0, T = 25 °C |
(85) |
| Cm3+ + 2 Propionate2– = [Cm(Propionate)2]+
|
log β12 = 4.63 |
| citrate |
Cm3+ + HCitrate3– = [CmHCitrate] |
log K1 = 7.4 |
I = 0.1 M (NaClO4), T = 23–25 °C |
(46) |
| Cm3+ + 2 HCitrate3– = [Cm(HCitrate)2]3–
|
log K2 = 11.3 |
| Cm3+ + H2Citrate2– +
HCitrate3–= [Cm(H2Citrate)HCitrate]2–
|
log K = 11.0 |
| desferrioxamine
B (DFOB) |
Cm3+ + DFOB3– =
[CmDFOB] |
log β101 = 16.80 |
I = 0.1 M (NaClO4), T = 25 °C |
(73) |
| Cm3+ + DFOB3– + H+ =
[CmHDFOB]+
|
log β111 = 25.73 |
| Cm3+ + DFOB3– + 2 H+ = [CmH2DFOB]2+
|
log β121 = 31.62 |
| Am3+ + DFOB3– + H+ =
[AmHDFOB)]+
|
log β111 = 25.5 |
I = 1 M (KNO3), T = 25 °C |
(86) |
| Am3+ + DFOB3– + 2 H+ = [AmH2DFOB]2+
|
log β121 = 32.2 |
| Am3+ + DFOB3– + 3 H+ = [AmH3DFOB]3+
|
log β131 = 37.9 |
| Am3+ + 2 DFOB3– + 4 H+ = [AmH4(DFOB)2]4+
|
log β142 = 60.5 |
| pyoverdin (PYOV) |
Cm3+ + PYOV4– = [CmPYOV]−
|
log β 101 = 19.30 |
I = 0.1 M (NaClO4), T = 25 °C |
(74) |
| Cm3+ + HPYOV3– + H+ = [CmHPYOV] |
log β 111 = 27.40 |
| Cm3+ + PYOV2– + 2 H+ = [CmH2PYOV]+
|
log β 121 = 32.50 |
| salicylhydroxamate (SHA) |
Cm3+ + SHA2+ + H+= [CmSHA]2+
|
log β 111 = 16.52 |
I = 0.1 M (NaClO4), T = 25 °C |
(75) |
| Cm3+ + 2 SHA– + H+ =
[CmH(SHA)2] |
log β 112 =
24.09 |
| benzohydroxamate (BHA) |
Cm3+ + BHA2+ = [CmBHA]2+
|
log β 111 = 6.52 |
I = 0.1 M (NaClO4), T = 25 °C |
(75) |
| Cm3+ + 2 BHA– = [CmH(BHA)2] |
log β 112 = 11.60 |
| humic acid (HA) |
Am3+ + HAx– = [AmHA]x−3
|
log
β 11 = 6.27 |
I = 0.1 M (NaClO4), pH 6. Note:
Two different sources of humic acids (Aldrich and Bradford –
see original reference) |
(70) |
| log β 11 = 6.36 |
