Table 2. Unlike Group Parameters (Excluding Association) for Use with the SAFT-γ Mie Approach^a.

group k	group l	(εkl/kB)	λrkl	ref	group k	group l	(εkl/kB)	λrkl	ref
H2O	COOH	289.76	CR	(76)	CH3	COO–	255.99	CR	(51,52)
H2O	NH2	358.55	CR	(75)	CH3	NH3+	244.15	CR	(47)
H2O	CH3	358.18	100.00	(76)	CH3	H3O+	CR	CR
H2O	CH2	423.63	100.00	(76)	CH3	Na+	CR	CR
H2O	CH	275.75	CR	(77)	CH3	Cl–	CR	CR
H2O	CH2OH	353.37	CR	(76)	CH3	OH–	CR	CR
H2O	CHOH	479.16	CR	(48)	CH3	CONH	430.60	CR	*
H2O	COO–	171.61	CR	(51,52)	CH2	CH	506.21	CR	(42)
H2O	NH3+	450.21	CR	(47)	CH2	CH2OH	423.17	CR	(76)
H2O	H3O+	391.04	CR	(65)	CH2†	CHOH	517.64	CR	(48)
H2O	OH–	134.41	CR	(65)	CH2	COO–	413.74	CR	(51,52)
H2O	CONH	379.59	CR	*	CH2	NH3+	348.39	CR	(47)
H2O	Na+	539.68	CR	(65)	CH2	H3O+	CR	CR
H2O	Cl–	95.406	CR	(65)	CH2	OH–	CR	CR
COOH	NH2	285.00	CR	*	CH2	CONH	315.00	CR	*
COOH	CH3	255.99	CR	(42)	CH2	Na+	CR	CR
COOH	CH2	413.74	CR	(42)	CH2	Cl–	CR	CR
COOH	CH	504.99	CR	(42)	CH	CH2OH	329.22	CR	(77)
COOH	CH2OH	488.18	CR	(78)	CH	CHOH	0	CR	(48)
COOH	CHOH	1154.3	50.000	*	CH	COO–	504.99	CR	(47)
COOH	COO–	405.78	8.0000	(51,52)	CH	NH3+	151.01	CR	(47)
COOH	NH3+	388.58	CR	(47)	CH	H3O+	CR	CR
COOH	H3O+	CR	CR	(47)	CH	OH–	CR	CR
COOH	OH–	CR	CR	(47)	CH	CONH	CR	CR
COOH	CONH	670.04	CR	*	CH	Na+	CR	CR
COOH	Na+	CR	CR		CH	Cl–	CR	CR
COOH	Cl–	CR	CR		CH2OH	CHOH	389.23	CR	(48)
NH2	CH3	244.15	CR	(75)	CH2OH	CONH	CR	CR
NH2	CH2	348.39	CR	(75)	COO–	NH3+	26.330	CR	(47)
NH2	CH	278.26	CR	*	COO–	H3O+	27.740	CR	(47)
NH2	CH2OH	528.21	52.305	(79)	COO–	OH–	44.520	CR	(47)
NH2	CHOH	415.54	10.643	*	COO–	Na+	9.9125	CR	(51,52)
NH2	COO–	CR	CR		COO–	Cl–	21.265	CR	(51,52)
NH2	NH3+	284.78	CR	(47)	NH3+	H3O+	56.958	CR	(47)
NH2	H3O+	CR	CR		NH3+	OH–	62.238	CR	(47)
NH2	OH–	CR	CR		NH3+	Na+	CR	CR
NH2	CONH	150.77	CR	*	NH3+	Cl–	65.257	CR	(47)
NH2	Na+	CR	CR		H3O+	OH–	66.439	CR	(65)
NH2	Cl–	CR	CR		H3O+	Na+	37.480	CR	(47)
CH3	CH2	350.77	CR	(41)	H3O+	Cl–	70.552	CR	(65)
CH3	CH	387.48	CR	(42)	OH–	Na+	27.898	CR	(65)
CH3	CH2OH	333.20	CR	(76)	OH–	Cl–	123.21	CR	(47)
CH3	CHOH	479.38	CR	(48)	Na+	Cl–	27.938	CR	(65)

^aAn asterisk indicates that the parameters are characterized in the current work. ^† Indicates that the CH₂−COO⁻ interaction corresponds to that of the Adjacent-CH₂ group interaciton with COO⁻ as described in refs (51, 52). CR indicates that combining rules are used.⁴¹