Table 2.
Carbon | 1 | 2 | 3 | 4 | 5 |
---|---|---|---|---|---|
1 | 38.6 | 71.8 | 71.1 | 77.2 | 70.6 |
2 | 35.1 | 30.3 | 25.1 | 24.5 | 29.1 |
3 | 217.0 | 73.6 | 73.1 | 72.4 | 72.2 |
4 | 47.7 | 42.5 | 43.9 | 43.9 | 42.4 |
5 | 52.5 | 40.2 | 38.7 | 38.7 | 39.0 |
6 | 24.5 | 72.9 | 73.7 | 73.9 | 72.5 |
7 | 118.2 | 74.7 | 74.1 | 74.0 | 74.6 |
8 | 145.7 | 44.5 | 39.7 | 39.8 | 45.4 |
9 | 48.0 | 36.6 | 34.3 | 34.8 | 36.4 |
10 | 35.2 | 40.3 | 45.2 | 45.2 | 41.2 |
11 | 17.9 | 34.1 | 30.5 | 30.4 | 30.5 |
12 | 31.6 | 213.8 | 77.9 | 71.2 | 97.8 |
13 | 43.6 | 61.5 | 52.5 | 51.7 | 140.3 |
14 | 50.9 | 154.1 | 156.1 | 157.1 | 146.1 |
15 | 34.4 | 123.8 | 122.5 | 122.2 | 77.9 |
16 | 27.6 | 34.2 | 35.5 | 35.8 | 35.8 |
17 | 48.5 | 42.9 | 51.2 | 48.9 | 49.3 |
18 | 23.3 | 19.4 | 15.5 | 15.1 | 16.5 |
19 | 12.8 | 15.6 | 16.1 | 15.5 | 16.7 |
20 | 47.1 | 124.6 | 169.1 | 137.5 | _ a |
21 | 101.8 | 142.4 | 99.1 | 171.4 | 98.7 |
22 | 33.6 | 112.6 | 120.4 | 146.5 | 118.7 |
23 | 76.7 | 141.0 | 170.9 | 96.5 | 170.8 |
24 | 86.5 | ||||
25 | 71.1 | ||||
26 | 25.9 | ||||
27 | 25.7 | ||||
28 | 24.6 | 78.1 | 78.4 | 78.4 | 78.1 |
29 | 21.7 | 18.8 | 20.2 | 20.2 | 19.0 |
30 | 27.4 | 25.8 | 26.7 | 26.9 | 20.7 |
12-OCH3 | 55.2 | ||||
1-OAC | 170.8 | ||||
21.2 | |||||
3-OAC | 169.2 | 170.7 | |||
20.9 | 21.3 | ||||
12-OAC | 170.9 | ||||
21.5 | |||||
1’ | 165.1 | 165.4 | 165.4 | 166.7 | |
2’ | 130.5 | 117.0 | 117.2 | 128.6 | |
3’ | 129.6 | 146.8 | 144.8 | 137.5 | |
4’ | 128.6 | 133.8 | 134.1 | 14.6 | |
5’ | 133.2 | 128.4 | 128.5 | 12.2 | |
6’ | 128.6 | 129.2 | 129.2 | ||
7’ | 129.6 | 131. | 130.9 | ||
8’ | 129.2 | 129.2 | |||
9’ | 128.4 | 128.5 |
a Signal not clearly observable from 1D and 2D NMR.