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. 2024 Nov 8;29(22):5283. doi: 10.3390/molecules29225283

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© 2024 by the authors.

Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).

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Scheme 11 — Proposed mechanistic details for dearomatization and ring-opening reactions (A–E) using [(9f-2H)M(CH₂Ar)(THF)] (M = Sc, Y, La, Lu), where Ar, R, and iqn stand for 3,5-Me₂C₆H₃, SiMe₂^tBu, and isoquinoline, respectively [70,71,72,73,74].