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Reaction conditions: ArCF2R (0.9 mmol), 1 (0.6 mmol), amine (0.3 mmol), Pd(PPh3)4 (1.5 mol%), XantPhos (8 mol%), [(o-OMe)Ph]2PPh (8 mol%), LiOH (0.3 mmol), THF (0.1 M), λmax = 440 nm Kessil (40 W), N2, RT – 40 °C, 12 h. Hydrogenation yield is shown in square brackets. See SI for hydrogenation procedures.
