Table 2. 13C NMR Spectroscopic Data for Compounds 1–5 in MeOD.
1a | 2a | 3a | 4a | 5b | |
---|---|---|---|---|---|
position | δC | δC | δC | δC | δC |
1 | 126.7, C | 132.3, C | 131.0, C | 124.2, C | 124.2, C |
2 | 108.8, CH | 104.8, CH | 104.7, CH | 109.1, CH | 109.1, CH |
3 | 139.0, C | 149.4, C | 149.5, C | 149.3, C | 149.3, C |
4 | 149.2, C | 136.6, C | 136.7, C | 143.3, C | 143.2, C |
5 | 139.0, C | 149.4, C | 149.5, C | 146.9, C | 147.0, C |
6 | 108.8, CH | 104.8, CH | 104.7, CH | 125.2, C | 125.3, C |
7 | 142.3, CH | 86.3, CH | 86.4, CH | 135.4, CH | 135.0, CH |
8 | 127.4, C | 60.3, CH | 60.6, CH | 126.8, C | 127.1, C |
9 | 168.2, C | 172.5, C | 172.1, C | 170.3, C | 170.0, C |
1′ | 126.7, C | 132.3, C | 132.4, C | 135.3, C | 135.2, C |
2′ | 108.9, CH | 104.8, CH | 104.9, CH | 106.0, CH | 106.1, CH |
3′ | 139.1, C | 149.4, C | 149.4, C | 149.0, C | 149.0, C |
4′ | 149.2, C | 136.6, C | 136.7, C | 135.3, C | 135.3, C |
5′ | 139.1, C | 149.4, C | 149.4, C | 149.0, C | 149.5, C |
6′ | 108.9, CH | 104.8, CH | 104.9, CH | 106.0, CH | 106.1, CH |
7′ | 142.5, CH | 86.3, CH | 86.4, CH | 41.4, CH | 41.4, CH |
8′ | 127.6, C | 60.3, CH | 60.3, CH | 50.2, CH | 50.1, CH |
9′ | 168.2, C | 172.5, C | 172.5, C | 174.3, C | 174.2, C |
1″ | 134.2, C | 134.2, C | 130.8, C | 134.7, C | 131.4, C |
2″ | 128.4, CH | 128.5, CH | 130.7, CH | 128.4, CH | 130.7, CH |
3″ | 116.0, CH | 116.1, CH | 116.2, CH | 116.1, CH | 116.2, CH |
4″ | 158.0, C | 158.0, C | 156.9, C | 158.0, C | 156.8, C |
5″ | 116.0, CH | 116.1, CH | 116.2, CH | 116.1, CH | 116.2, CH |
6″ | 128.4, CH | 128.5, CH | 130.7, CH | 128.4, CH | 130.7, CH |
7″ | 73.0, CH | 73.1, CH | 35.7, CH2 | 73.4, CH | 35.6, CH2 |
8″ | 48.5, CH2 | 48.1, CH2 | 42.6, CH2 | 48.4, CH2 | 42.8, CH2 |
1‴ | 134.3, C | 134.2, C | 134.5, C | 134.3, C | 134.4, C |
2‴ | 128.3, CH | 128.5, CH | 128.5, CH | 128.4, CH | 130.8, CH |
3‴ | 116.1, CH | 116.1, CH | 116.1, CH | 116.1, CH | 116.2, CH |
4‴ | 158.0, C | 158.0, C | 158.0, C | 157.9, C | 156.9, C |
5‴ | 116.1, CH | 116.1, CH | 116.1, CH | 116.1, CH | 116.2, CH |
6‴ | 128.3, CH | 128.5, CH | 128.5, CH | 128.4, CH | 130.8, CH |
7‴ | 73.5, CH | 73.1, CH | 73.2, CH | 72.8, CH | 72.8, CH |
8‴ | 48.5, CH2 | 48.1, CH2 | 48.1, CH2 | 48.0, CH2 | 47.9, CH2 |
OCH3-3′, 5′ | 56.7, CH3 | 56.8, CH3 | 56.9, CH3 | 56.7, CH3 | 56.7, CH3 |
OCH3-3 | 56.7, CH3 | 56.8, CH3 | 56.8, CH3 | 56.8, CH3 | 56.8, CH3 |
OCH3-5 | 56.7, CH3 | 56.8, CH3 | 56.8, CH3 | 60.8, CH3 | 60.8, CH3 |
Measured at 100 MHz.
Measured at 125 MHz.