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. 2024 Nov 11;9(47):47350–47360. doi: 10.1021/acsomega.4c09084

Table 3. Effect of Temperature on the Molar Extinction Coefficients.

  temperature
 
wavelength (nm) 20 °C 25 °C 30 °C 35 °C effect of temp. (1/°C)
Molar Extinction Coeffient for I22, M–1cm–1)a
430 543 540 536 531 –0.15%
456 724 717 711 703 –0.19%
460 729 722 715 708 –0.19%
466 723 717 711 704 –0.18%
469 715 709 704 697 –0.17%
470 712 706 700 694 –0.17%
476 685 680 676 670 –0.15%
Molar Extinction Coefficient for I33, M–1cm–1)b
430 2444 2484 2525 2569 0.34%
456 1145 1171 1195 1222 0.44%
460 997 1022 1045 1070 0.48%
466 797 819 840 863 0.53%
469 709 730 749 771 0.57%
470 682 703 722 742 0.58%
476 538 556 573 592 0.64%
a

A solution containing 0.0563 g iodine flake in 1 L.

b

A solution containing 0.527g I2 flake and 35.542 g NaI in 1 L.