Table 3. Effect of Temperature on the Molar Extinction Coefficients.
temperature |
|||||
---|---|---|---|---|---|
wavelength (nm) | 20 °C | 25 °C | 30 °C | 35 °C | effect of temp. (1/°C) |
Molar Extinction Coeffient for I2 (ε2, M–1cm–1)a | |||||
430 | 543 | 540 | 536 | 531 | –0.15% |
456 | 724 | 717 | 711 | 703 | –0.19% |
460 | 729 | 722 | 715 | 708 | –0.19% |
466 | 723 | 717 | 711 | 704 | –0.18% |
469 | 715 | 709 | 704 | 697 | –0.17% |
470 | 712 | 706 | 700 | 694 | –0.17% |
476 | 685 | 680 | 676 | 670 | –0.15% |
Molar Extinction Coefficient for I3– (ε3, M–1cm–1)b | |||||
430 | 2444 | 2484 | 2525 | 2569 | 0.34% |
456 | 1145 | 1171 | 1195 | 1222 | 0.44% |
460 | 997 | 1022 | 1045 | 1070 | 0.48% |
466 | 797 | 819 | 840 | 863 | 0.53% |
469 | 709 | 730 | 749 | 771 | 0.57% |
470 | 682 | 703 | 722 | 742 | 0.58% |
476 | 538 | 556 | 573 | 592 | 0.64% |
A solution containing 0.0563 g iodine flake in 1 L.
A solution containing 0.527g I2 flake and 35.542 g NaI in 1 L.