Table 4. Densities ρ of Aqueous Solutions Containing MEA (2), HEIA (3), and CO2 (4)a.
ρ/(g cm–3) |
|||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
x2 | x3 | x4 | α0 | α1 | α2 | T = 298.15 K | T = 303.15 K | T = 313.15 K | T = 323.15 K | T = 333.15 K | T = 343.15 K | T = 353.15 K | T = 363.15 K |
0.1128 | 0 | 0 | 0 | 0 | 0 | 1.0106 | 1.0083 | 1.0034 | 0.9981 | 0.9922 | 0.9857 | – | – |
0.1102 | 0 | 0.0235 | 0.213 | 0 | 0 | 1.0634 | 1.0609 | 1.0556 | 1.0502 | 1.0442 | 1.038 | – | – |
0.1091 | 0 | 0.0271 | 0.248 | 0 | 0 | 1.0667 | – | 1.0589 | – | – | 1.042 | – | – |
0.1076 | 0 | 0.0459 | 0.426 | 0 | 0 | 1.1113 | 1.1089 | 1.1039 | 1.0986 | 1.0927 | 1.0867 | – | – |
0.1062 | 0 | 0.0527 | 0.496 | 0 | 0 | 1.1171 | – | 1.1097 | – | 1.09841 | – | – | |
0 | 1 | 0 | 0 | 0 | 0 | – | – | – | – | 1.2223 | 1.2179 | 1.2043 | 1.1997 |
0 | 0.2722 | 0 | 0 | 0 | 0 | 1.1811 | 1.1776 | 1.1704 | 1.1631 | 1.1557 | 1.1482 | 1.1405 | – |
0 | 0.1173 | 0 | 0 | 0 | 0 | 1.1153 | 1.1123 | 1.1061 | 1.0997 | 1.0929 | 1.0858 | 1.0772 | – |
0 | 0.0419 | 0 | 0 | 0 | 0 | 1.0527 | 1.0505 | 1.0457 | 1.0404 | 1.0338 | – | – | – |
0.1111 | 0.0130 | 0 | 0 | 0 | 0 | 1.0248 | 1.0224 | 1.0172 | 1.0116 | 1.0055 | 0.999 | – | – |
0.1078 | 0.0127 | 0.0297 | 0.275 | 0.248 | 0.225 | 1.0799 | – | 1.0723 | – | – | 1.0551 | – | – |
0.1047 | 0.0123 | 0.0576 | 0.55 | 0.495 | 0.450 | 1.1304 | – | 1.1229 | – | – | – | – | – |
0.1101 | 0.0278 | 0 | 0 | 0 | 0 | 1.0405 | 1.0379 | 1.0324 | 1.0265 | 1.0202 | 1.0134 | – | – |
0.1064 | 0.0266 | 0.0245 | 0.233 | 0.19 | 0.16 | 1.0927 | 1.0896 | 1.0838 | 1.0778 | 1.0719 | 1.0657 | – | – |
0.1067 | 0.0270 | 0.0304 | 0.285 | 0.228 | 0.19 | 1.0982 | – | 1.0902 | – | 1.0755 | 1.0724 | – | – |
0.1038 | 0.0259 | 0.0488 | 0.467 | 0.37 | 0.31 | 1.1369 | 1.1344 | 1.129 | 1.1233 | – | – | – | – |
0.1036 | 0.0262 | 0.0596 | 0.57 | 0.456 | 0.380 | 1.1369 | – | 1.1288 | – | – | – | – | – |
xi is the mole fraction of component i in aqueous solution, T is temperature, and αi (i = 0, 1, 2) are measures of the CO2 loading as determined from the definitions in Table 3. Expanded uncertainties at 95% confidence for MEA aqueous solutions are U(T) = 0.02 K, U(α0) = 0.03, U(x2) = 0.0002, and U(ρ) = 0.0004 g cm–3. Expanded uncertainties at 95% confidence for HEIA aqueous solutions are U(T) = 0.02 K, U(x3) = 0.0002, and U(ρ) = 0.002 g cm–3. Expanded uncertainties at 95% confidence for HEIA-MEA blend aqueous solutions are U(T) = 0.02 K, U(α0) = U(α1) = 0.01, U(α2) = 0.0098, U(x2) = U(x3) = 0.0002, and U(ρ) = 0.0002 g cm–3. All measurements were performed at a pressure of 0.1 MPa.