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. 2024 May 9;69(10):3435–3449. doi: 10.1021/acs.jced.4c00077

Table 4. Densities ρ of Aqueous Solutions Containing MEA (2), HEIA (3), and CO2 (4)a.

            ρ/(g cm–3)
x2 x3 x4 α0 α1 α2 T = 298.15 K T = 303.15 K T = 313.15 K T = 323.15 K T = 333.15 K T = 343.15 K T = 353.15 K T = 363.15 K
0.1128 0 0 0 0 0 1.0106 1.0083 1.0034 0.9981 0.9922 0.9857
0.1102 0 0.0235 0.213 0 0 1.0634 1.0609 1.0556 1.0502 1.0442 1.038
0.1091 0 0.0271 0.248 0 0 1.0667 1.0589 1.042
0.1076 0 0.0459 0.426 0 0 1.1113 1.1089 1.1039 1.0986 1.0927 1.0867
0.1062 0 0.0527 0.496 0 0 1.1171 1.1097 1.09841  
0 1 0 0 0 0 1.2223 1.2179 1.2043 1.1997
0 0.2722 0 0 0 0 1.1811 1.1776 1.1704 1.1631 1.1557 1.1482 1.1405
0 0.1173 0 0 0 0 1.1153 1.1123 1.1061 1.0997 1.0929 1.0858 1.0772
0 0.0419 0 0 0 0 1.0527 1.0505 1.0457 1.0404 1.0338
0.1111 0.0130 0 0 0 0 1.0248 1.0224 1.0172 1.0116 1.0055 0.999
0.1078 0.0127 0.0297 0.275 0.248 0.225 1.0799 1.0723 1.0551
0.1047 0.0123 0.0576 0.55 0.495 0.450 1.1304 1.1229
0.1101 0.0278 0 0 0 0 1.0405 1.0379 1.0324 1.0265 1.0202 1.0134
0.1064 0.0266 0.0245 0.233 0.19 0.16 1.0927 1.0896 1.0838 1.0778 1.0719 1.0657
0.1067 0.0270 0.0304 0.285 0.228 0.19 1.0982 1.0902 1.0755 1.0724
0.1038 0.0259 0.0488 0.467 0.37 0.31 1.1369 1.1344 1.129 1.1233
0.1036 0.0262 0.0596 0.57 0.456 0.380 1.1369 1.1288
a

xi is the mole fraction of component i in aqueous solution, T is temperature, and αi (i = 0, 1, 2) are measures of the CO2 loading as determined from the definitions in Table 3. Expanded uncertainties at 95% confidence for MEA aqueous solutions are U(T) = 0.02 K, U0) = 0.03, U(x2) = 0.0002, and U(ρ) = 0.0004 g cm–3. Expanded uncertainties at 95% confidence for HEIA aqueous solutions are U(T) = 0.02 K, U(x3) = 0.0002, and U(ρ) = 0.002 g cm–3. Expanded uncertainties at 95% confidence for HEIA-MEA blend aqueous solutions are U(T) = 0.02 K, U0) = U1) = 0.01, U2) = 0.0098, U(x2) = U(x3) = 0.0002, and U(ρ) = 0.0002 g cm–3. All measurements were performed at a pressure of 0.1 MPa.