Table 5. Viscosities μ of Aqueous Solutions Containing MEA (2), HEIA (3), and CO2 (4)a.
μ/(mPa s) |
||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
x2 | x3 | x4 | α0 | α1 | α2 | 298.15 K | 303.15 K | 313.15 K | 323.15 K | 333.15 K | 343.15 K | 353.15 K |
0.1128 | 0 | 0 | 0 | 0 | 0 | 2.418 | 2.089 | 1.614 | 1.281 | 1.043 | 0.866 | – |
0.1102 | 0 | 0.0235 | 0.213 | 0 | 0 | 2.988 | 2.615 | 2.012 | 1.618 | 1.334 | 1.092 | – |
0.1091 | 0 | 0.0271 | 0.248 | 0 | 0 | 3.053 | – | 2.079 | – | – | 1.138 | – |
0.1076 | 0 | 0.0459 | 0.426 | 0 | 0 | 3.618 | 3.139 | 2.430 | 1.945 | 1.583 | 1.317 | – |
0.1062 | 0 | 0.0527 | 0.496 | 0 | 0 | 3.674 | – | 2.531 | – | 1.652 | – | – |
0 | 0.2722 | 0 | 0 | 0 | 0 | 21.946 | 17.339 | 11.266 | 7.862 | 5.687 | 4.282 | 3.337 |
0 | 0.1173 | 0 | 0 | 0 | 0 | 4.443 | 3.767 | 2.836 | 2.182 | 1.766 | 1.438 | 1.182 |
0 | 0.0419 | 0 | 0 | 0 | 0 | 1.667 | 1.483 | 1.175 | 0.960 | 0.798 | – | – |
0.1111 | 0.0130 | 0 | 0 | 0 | 0 | 2.770 | 2.390 | 1.814 | 1.432 | 1.155 | 0.950 | – |
0.1078 | 0.0127 | 0.0297 | 0.275 | 0.248 | 0.225 | 3.765 | – | 2.382 | – | – | 1.288 | – |
0.1047 | 0.0123 | 0.0576 | 0.55 | 0.495 | 0.450 | 4.694 | – | 2.955 | – | – | – | – |
0.1101 | 0.0278 | 0 | 0 | 0 | 0 | 3.334 | 2.825 | 2.137 | 1.665 | 1.338 | 1.099 | – |
0.1064 | 0.0266 | 0.0245 | 0.233 | 0.19 | 0.16 | 4.249 | 3.635 | 2.758 | 2.135 | 1.730 | 1.424 | – |
0.1067 | 0.0270 | 0.0304 | 0.285 | 0.228 | 0.19 | 4.389 | – | 2.748 | – | – | 1.379 | – |
0.1038 | 0.0259 | 0.0488 | 0.467 | 0.37 | 0.31 | 5.309 | 4.576 | 3.447 | 2.709 | – | – | – |
0.1036 | 0.0262 | 0.0596 | 0.57 | 0.456 | 0.380 | 5.336 | – | 3.546 | – | – | – | – |
xi is the mole fraction of component i in aqueous solution, T is temperature, and αi (i = 0, 1, 2) are measures of the CO2 loading as determined from the definitions in Table 3. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U(α0) = 0.03, U(x2) = 0.0002, and U(μ) = 0.05 mPa s. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U(x3) = 0.0002, and U(μ) = 0.05 mPa s. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U(α0) = U(α1) = 0.01, U(α2) = 0.0098, U(x2) = U(x3) = 0.0002, and U(μ) = 0.01 mPa s. All measurements were performed at a pressure of 0.1 MPa.