Table 6. Surface Tensions σ of Aqueous Solutions Containing MEA (2), HEIA (3), and CO2 (4)a.
σ (mN/m) |
|||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
x2 | x3 | x4 | α0 | α1 | α2 | 298.15 K | 303.15 K | 308.15 K | 313.15 K | 318.15 K | 323.15 K | 328.15 K | 333.15 K |
0.1128 | 0 | 0 | 0 | 0 | 0 | 63.570 | 62.440 | 61.460 | 60.570 | 59.530 | 59.150 | 58.180 | – |
0.1091 | 0 | 0.0271 | 0.248 | 0 | 0 | 67.710 | 66.645 | 65.970 | 65.800 | – | – | ||
0.1062 | 0 | 0.0527 | 0.496 | 0 | 0 | 72.333 | 71.620 | 71.720 | 71.150 | – | 69.890 | 68.935 | – |
0.1111 | 0.0130 | 0 | 0 | 0 | 0 | 63.913 | 63.165 | – | 61.223 | – | 59.180 | – | 59.454 |
0.1078 | 0.0127 | 0.0297 | 0.275 | 0.1078 | 0.0127 | 65.960 | 65.140 | 64.340 | 63.846 | 63.203 | 62.540 | – | – |
0.1047 | 0.0123 | 0.0576 | 0.55 | 0.1047 | 0.0123 | 70.813 | 70.260 | 69.508 | 69.153 | 68.733 | 68.085 | – | – |
0.1091 | 0.0273 | 0 | 0 | 0 | 0 | 64.900 | 64.340 | 63.773 | 63.338 | 62.458 | 61.705 | 61.183 | 60.440 |
0.1067 | 0.0270 | 0.0304 | 0.285 | 0.228 | 0.19 | – | 67.485 | – | 66.540 | – | 64.860 | – | – |
0.1029 | 0.0257 | 0.0586 | 0.57 | 0.456 | 0.380 | 70.333 | 70.190 | 69.542 | 69.036 | – | 67.565 | – | 65.785 |
xi is the mole fraction of component i in aqueous solution, T is temperature and αi (i = 0, 1, 2) are measures of the CO2 loading as determined from the definitions in Table 3. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U(α0) = 0.03, U(x2) = 0.0002, and U(σ) = 1.2 mN/m. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U(α0) = U(α1) = 0.01, U(α2) = 0.0098, U(x2) = U(x3) = 0.0002, and U(σ) = 1.2 mN/m.