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. 2024 May 9;69(10):3435–3449. doi: 10.1021/acs.jced.4c00077

Table 6. Surface Tensions σ of Aqueous Solutions Containing MEA (2), HEIA (3), and CO2 (4)a.

            σ (mN/m)
x2 x3 x4 α0 α1 α2 298.15 K 303.15 K 308.15 K 313.15 K 318.15 K 323.15 K 328.15 K 333.15 K
0.1128 0 0 0 0 0 63.570 62.440 61.460 60.570 59.530 59.150 58.180
0.1091 0 0.0271 0.248 0 0 67.710 66.645 65.970 65.800    
0.1062 0 0.0527 0.496 0 0 72.333 71.620 71.720 71.150 69.890 68.935
0.1111 0.0130 0 0 0 0 63.913 63.165 61.223 59.180 59.454
0.1078 0.0127 0.0297 0.275 0.1078 0.0127 65.960 65.140 64.340 63.846 63.203 62.540
0.1047 0.0123 0.0576 0.55 0.1047 0.0123 70.813 70.260 69.508 69.153 68.733 68.085
0.1091 0.0273 0 0 0 0 64.900 64.340 63.773 63.338 62.458 61.705 61.183 60.440
0.1067 0.0270 0.0304 0.285 0.228 0.19 67.485 66.540 64.860
0.1029 0.0257 0.0586 0.57 0.456 0.380 70.333 70.190 69.542 69.036 67.565 65.785
a

xi is the mole fraction of component i in aqueous solution, T is temperature and αi (i = 0, 1, 2) are measures of the CO2 loading as determined from the definitions in Table 3. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U0) = 0.03, U(x2) = 0.0002, and U(σ) = 1.2 mN/m. Expanded uncertainties at 95% confidence are U(T) = 0.02 K, U0) = U1) = 0.01, U2) = 0.0098, U(x2) = U(x3) = 0.0002, and U(σ) = 1.2 mN/m.