Selected building
blocks used to synthesize hydrophobic MOFs. H2PC (cyclopentiptycene
dicarboxylic acid ligand),40 H4PC (cyclopentiptycene tetracarboxylic
acid ligand),46 H8tdhb (3,3′,5,5′-tetrakis(3,5-dicarboxyphenyl)-2,2′,4,4′,6,6′-hexamethylbiphenyl,43 OPE-C18 (dialkoxyoctadecyl-oligo-(p-phenyleneethynylene)dicarboxylate,47 Tz
(3,5-bis(trifluoromethyl)-1,2,4-triazolate),48 H2OFBPDC (2,2′,3,3′,5,5′,6,6′-octafluorobiphenyl-4,4′-dicarboxylic
acid),49 H2TFNDC (1-(2,2,2-trifluoroacetamido)-naphthalene-3,7-dicarboxylic
acid),50 H4BDO (2,5-bis(3,5-dicarboxylphenyl)-1,3,4-oxadiazole),51 and H2TFPBA (4,4′-([3,5-bis(trifluoromethyl)phenyl]azanediyl)benzoic
acid).52