Table 5. Summary of the main outcomes of this study.
Investigation type | Main Outcomes |
---|---|
Surface characterization | Localized corrosion on all the surfaces after the ageing sequence. |
Cu R covered by the most continuous layer of corrosion products and shows the highest O element wt.% increase, due to its strain-hardened microstructure. | |
Cu18Ni20Zn is covered by the smallest corrosion spots and undergoes the lowest O increase thanks to its recrystallized microstructure and the presence of alloying elements (i.e., Ni) that enhance its corrosion resistance. | |
% variation of Rq: Cu18Ni20Zn (104%) < Cu15Zn (967%) < Cu R+A (1037%) < Cu R (1577%). | |
Cu15Zn exhibited the highest increase in Rsk, indicating that localized corrosion products were shaped as relatively high “bubbles”. | |
Color variation (ΔE) after ageing: Cu R > Cu15Zn> Cu R+A > Cu18Ni20Zn. | |
Biofilm inhibition assessment against P. aeruginosa | Strong decrease in biofilm formation capacity on aged Cu alloy surfaces compared to each pristine counterpart. |
Biofilm formation capacity Log10 (CFU/mL/cm2 for aged surfaces)—Log10 (CFU/mL/cm2 for pristine surfaces): | |
Cu18Ni20Zn (-0.98) < Cu R (-1.93) < Cu R+A (-2.48) < Cu15Zn (-3.03) | |
Cu release | Cu release variation due to ageing: Cu18Ni20Zn (1.0x) < Cu R (3.6x) < Cu R+A (8.3x) < Cu15Zn (12.6x). |
Among pristine surfaces: Cu R > Cu18Ni20Zn > Cu R+A ≃ Cu15Zn | |
Among aged surfaces: Cu15Zn ≃ Cu R ≃ Cu R+A > Cu18Ni20Zn |