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. Author manuscript; available in PMC: 2024 Dec 5.
Published before final editing as: J Am Chem Soc. 2023 Feb 13:10.1021/jacs.2c13054. doi: 10.1021/jacs.2c13054

Scheme 3. Scope of the Remote Hydroamination with Different Alkenesa.

Scheme 3.

aProducts 3eb−3fb, 3ub, and 3xb were formed in 1:1 dr. b(4-NMe2-3,5-DIP)-MeOBIPHEP as the ligand. c7.5 equiv of alkene. d3.75 mol % [Ir(coe2)Cl]2, 9 mol % ligand and NaBArF. eTen equiv of alkene. fFive mol % [Ir(coe)2Cl]2, 12 mol % ligand and NaBArF. gTwenty equiv of alkene.